pH-dependent surface charging and points of zero charge. IV. Update and new approach.

Our ability to accurately simulate the transport and retention of colloids in the vadose zone is currently limited by our lack of basic understanding of colloid retention processes that occur at the pore scale. This review discusses our current knowledge of physical and chemical mechanisms, factors, and models of colloid transport and retention at the interface, collector, and pore scales. The interface scale is well suited for studying the interaction energy and hydrodynamic forces and torques that act on colloids near interfaces. Solid surface roughness is reported to have a significant influence on both adhesive and applied hydrodynamic forces and torques, whereas non-Derjaguin–Landau–Verwey–Overbeek (DLVO) forces such as hydrophobic and capillary forces are likely to play a significant role in colloid interactions with the air–water interface. The flow field can be solved and mass transfer processes can be quantified at the collector scale. Here the potential for colloid attachment in the presence of hydrodynamic forces is determined from a balance of applied and adhesive torques. The fraction of the collector surface that contributes to attachment has been demonstrated to depend on both physical and chemical conditions. Processes of colloid mass transfer and retention can also be calculated at the pore scale. Differences in collector- and pore-scale studies occur as a result of the presence of small pore spaces that are associated with multiple interfaces and zones of relative flow stagnation. Here a variety of straining processes may occur in saturated and unsaturated systems, as well as colloid size exclusion. Our current knowledge of straining processes is still incomplete, but recent research indicates a strong coupling of hydrodynamics, solution chemistry, and colloid concentration on these processes, as well as a dependency on the size of the colloid, the solid grain, and the water content.

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Colloid Transport and Retention in Unsaturated Porous Media: A Review of Interface-, Collector-, and Pore-Scale Processes and Models

Modeling microbial transport in porous media: Traditional approaches and recent developments

Transport of colloidal particles in porous media is governed by the rate at which the colloids strike and stick to collector surfaces. Classic filtration theory has considered the influence of system hydrodynamics on determining the rate at which colloids strike collector surfaces, but has neglected the influence of hydrodynamic forces in the calculation of the collision efficiency. Computational simulations based on the sphere-in-cell model were conducted that considered the influence of hydrodynamic and Derjaguin-Landau-Verwey-Overbeek (DLVO) forces on colloid attachment to collectors of various shape and size. Our analysis indicated that hydrodynamic and DLVO forces and collector shape and size significantly influenced the colloid collision efficiency. Colloid attachment was only possible on regions of the collector where the torque from hydrodynamic shear acting on colloids adjacent to collector surfaces was less than the adhesive (DLVO) torque that resists detachment. The fraction of the collector surface area on which attachment was possible increased with solution ionic strength, collector size, and decreasing flow velocity. Simulations demonstrated that quantitative evaluation of colloid transport through porous media will require nontraditional approaches that account for hydrodynamic and DLVO forces as well as collector shape and size.

Resolving the coupled effects of hydrodynamics and DLVO forces on colloid attachment in porous media.

[1] Straining may influence the mobility of colloid-sized particles within groundwater aquifers as well as within granular filters that are used in wastewater treatment. We conducted column transport experiments using latex microspheres as the colloids and quartz sand as the porous medium to investigate the response of colloid straining to changes in colloid diameter (dp) and sand grain diameter (dg). For these experiments the negatively charged microspheres were suspended in deionized water, and the quartz sand was thoroughly cleaned to minimize physicochemical deposition (attachment), which permitted the determination of straining in an unambiguous way. The measurements of strained (immobile phase) and effluent (aqueous phase) colloid concentrations could be described with a transport model that accounted for an exponential decline in straining rates with increasing concentrations of strained colloids. Best fit values of the model coefficient that quantified clean bed straining rates (ko) were negligibly small for dp/dg < 0.008 and, above this threshold, varied linearly with dp/dg. Our findings suggest that accurate inferences on the mobility of colloid-sized particles will require consideration of the effects of straining when dp/dg exceeds 0.008.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2006WR004948

Straining of colloidal particles in saturated porous media

To test the effect of geochemical heterogeneity on microorganism transport in saturated porous media, we measured the removal of two microorganisms, the bacteriophage PRD1 and oocysts of the protozoan parasite Cryptosporidium parvum, in flow-through columns of quartz sand coated by different amounts of a ferric oxyhydroxide. The experiments were conducted over ranges of ferric oxyhydroxide coating fraction of lambda = 0-0.12 for PRD1 and from lambda = 0-0.32 for the oocysts at pH 5.6-5.8 and 10(-4) M ionic strength. To determine the effect of pH on the transport of the oocysts, experiments were also conducted over a pH range of 5.7-10.0 at a coating fraction of lambda = 0.04. Collision (attachment) efficiencies increased as the fraction of ferric oxyhydroxide coated quartz sand increased, from alpha = 0.0071 to 0.13 over lambda = 0-0.12 for PRD1 and from alpha = 0.059 to 0.75 over lambda = 0-0.32 for the oocysts. Increasing the pH from 5.7 to 10.0 resulted in a decrease in the oocyst collision efficiency as the pH exceeded the expected point of zero charge of the ferric oxyhydroxide coatings. The collision efficiencies correlated very well with the fraction of quartz sand coated by the ferric oxyhydroxide for PRD1 but not as well for the oocysts.

Y.G. Bogatsu

Papers

Effect of ferric oxyhydroxide grain coatings on the transport of bacteriophage PRD1 and Cryptosporidium parvum oocysts in saturated porous media.