Phosphor-converted white light-emitting diodes (pc-WLEDs) are emerging as an indispensable solid-state light source for the next generation lighting industry and display systems due to their unique properties including but not limited to energy savings, environment-friendliness, small volume, and long persistence. Until now, major challenges in pc-WLEDs have been to achieve high luminous efficacy, high chromatic stability, brilliant color-rending properties, and price competitiveness against fluorescent lamps, which rely critically on the phosphor properties. A comprehensive understanding of the nature and limitations of phosphors and the factors dominating the general trends in pc-WLEDs is of fundamental importance for advancing technological applications. This report aims to provide the most recent advances in the synthesis and application of phosphors for pc-WLEDs with emphasis specifically on: (a) principles to tune the excitation and emission spectra of phosphors: prediction according to crystal field theory, and structural chemistry characteristics (e.g. covalence of chemical bonds, electronegativity, and polarization effects of element); (b) pc-WLEDs with phosphors excited by blue-LED chips: phosphor characteristics, structure, and activated ions (i.e. Ce 3+ and Eu 2+ ), including YAG:Ce, other garnets, non-garnets, sulfides, and (oxy)nitrides; (c) pc-WLEDs with phosphors excited by near ultraviolet LED chips: single-phased white-emitting phosphors (e.g. Eu 2+ –Mn 2+ activated phosphors), red-green-blue phosphors, energy transfer, and mechanisms involved; and (d) new clues for designing novel high-performance phosphors for pc-WLEDs based on available LED chips. Emphasis shall also be placed on the relationships among crystal structure, luminescence properties, and device performances. In addition, applications, challenges and future advances of pc-WLEDs will be discussed.

Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties

This paper presents a polynomial dimensional decomposition (PDD) method for global sensitivity analysis of stochastic systems subject to independent random input following arbitrary probability distributions. The method involves Fourier-polynomial expansions of lower-variate component functions of a stochastic response by measure-consistent orthonormal polynomial bases, analytical formulae for calculating the global sensitivity indices in terms of the expansion coefficients, and dimension-reduction integration for estimating the expansion coefficients. Due to identical dimensional structures of PDD and analysis-of-variance decomposition, the proposed method facilitates simple and direct calculation of the global sensitivity indices. Numerical results of the global sensitivity indices computed for smooth systems reveal significantly higher convergence rates of the PDD approximation than those from existing methods, including polynomial chaos expansion, random balance design, state-dependent parameter, improved Sobol’s method, and sampling-based methods. However, for non-smooth functions, the convergence properties of the PDD solution deteriorate to a great extent, warranting further improvements. The computational complexity of the PDD method is polynomial, as opposed to exponential, thereby alleviating the curse of dimensionality to some extent. Mathematical modeling of complex systems often requires sensitivity analysis to determine how an output variable of interest is influenced by individual or subsets of input variables. A traditional local sensitivity analysis entails gradients or derivatives, often invoked in design optimization, describing changes in the model response due to the local variation of input. Depending on the model output, obtaining gradients or derivatives, if they exist, can be simple or difficult. In contrast, a global sensitivity analysis (GSA), increasingly becoming mainstream, characterizes how the global variation of input, due to its uncertainty, impacts the overall uncertain behavior of the model. In other words, GSA constitutes the study of how the output uncertainty from a mathematical model is divvied up, qualitatively or quantitatively, to distinct sources of input variation in the model [1].

Reliability Engineering and System Safety

A lighting device comprising first and second groups of solid state light emitters, which emit light having peak wavelength in ranges of from 430 nm to 480 nm, and first and second groups of lumiphors which emit light having dominant wavelength in the range of from 555 nm to 585 nm. In some embodiments, if current is supplied to a power line, a combination of (1) light exiting the lighting device which was emitted by the first group of emitters, and (2) light exiting the lighting device which was emitted by the first group of lumiphors would have a correlated color temperature which differs by at least 50 K from a correlated color temperature which would be emitted by a combination of (3) light exiting the lighting device which was emitted by the second group of emitters, and (4) light exiting the lighting device which was emitted by the second group of lumiphors.

Lighting device and lighting method

Visible Light Communication (VLC) is an emerging field in Optical Wireless Communication (OWC) which utilizes the superior modulation bandwidth of Light Emitting Diodes (LEDs) to transmit data. In modern day communication systems, the most popular frequency band is Radio Frequency (RF) mainly due to little interference and good coverage. However, the rapidly dwindling RF spectrum along with increasing wireless network traffic has substantiated the need for greater bandwidth and spectral relief. By combining illumination and communication, VLC provides ubiquitous communication while addressing the shortfalls and limitations of RF communication. This paper provides a comprehensive survey on VLC with an emphasis on challenges faced in indoor applications over the period 1979–2014. VLC is compared with infrared (IR) and RF systems and the necessity for using this beneficial technology in communication systems is justified. The advantages of LEDs compared to traditional lighting technologies are discussed and comparison is done between different types of LEDs currently available. Modulation schemes and dimming techniques for indoor VLC are discussed in detail. Methods needed to improve VLC system performance such as filtering, equalization, compensation, and beamforming are also presented. The recent progress made by various research groups in this field is discussed along with the possible applications of this technology. Finally, the limitations of VLC as well as the probable future directions are presented.

LED Based Indoor Visible Light Communications: State of the Art

Even though light-emitting diodes (LEDs) may have a very long life, poorly designed LED lighting systems can experience a short life. Because heat at the p-n-junction is one of the main factors that affect the life of the LED, by knowing the relationship between life and heat, LED system manufacturers can design and build long-lasting systems. In this study, several white LEDs from the same manufacturer were subjected to life tests at different ambient temperatures. The exponential decay of light output as a function of time provided a convenient method to rapidly estimate life by data extrapolation. The life of these LEDs decreases in an exponential manner with increasing temperature. In a second experiment, several high-power white LEDs from different manufacturers were life-tested under similar conditions. Results show that the different products have significantly different life values.

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Life of LED-based white light sources

https://www.lrc.rpi.edu/programs/solidstate/pdf/narendran2004_jcrystalgrowth.pdf

Solid-state lighting: failure analysis of white LEDs

A light emitting apparatus has a radiation source for emitting short wavelength radiation. A down conversion material receives and down converts at least some of the short wavelength radiation emitted by the radiation source and back transfers a portion of the received and down converted radiation. An optic device adjacent the down conversion material at least partially surrounds the radiation source. The optic device is configured to extract at least some of the back transferred radiation. A sealant substantially seals a space between the radiation source and the optic device.

High-power white LEDs and manufacturing method thereof

The goal of this study was to develop a non-contact method for determining the junction temperature of phosphor-converted white LEDs as a first step toward determining the useful life of systems using white LEDs. System manufacturers generally quote the same life values for their lighting systems that the LED manufacturers estimate for a single LED. However, the life of an LED system can be much different compared with the life of an LED tested under ideal conditions because system packaging can affect system life. Heat at the pn-junction is one of the key factors that affect the degradation rate, and thus the useful life, of GaN-based white LEDs. The non-contact method described in this manuscript, combined with LED degradation rates, can be used to predict white-LED system life without affecting the integrity of the lighting system or submitting it to long-term life tests that are time-consuming. Different types of LED packages would have different degradation mechanisms. Therefore, as a first step this study considered only the 5mm epoxy encapsulated GaN+YAG Cerium phosphor white LED. The method investigated here explored whether the spectral power distribution (SPD) of the white LED could provide the necessary information to estimate LED junction temperature. Based on past studies that have shown that heat affects the radiant energy emitted by the InGaN blue LED and the YAG Cerium phosphor differently, the authors hypothesized that the ratio of the total radiant energy (W) to the radiant energy within the blue emission (B) would be proportional to the junction temperature. Experiments conducted in this study verified this hypothesis and showed that the junction temperature can be measured non-invasively through spectral measurements.

/pdf/a-noncontact-method-for-determining-junction-temperature-of-53hotw09k1.pdf

A noncontact method for determining junction temperature of phosphor-converted white LEDs

A light emitting apparatus includes a source of light for emitting light; a down conversion material receiving the emitted light, and converting the emitted light into transmitted light and backward transmitted light; and an optic device configured to receive the backward transmitted light and transfer the backward transmitted light outside of the optic device. The source of light is a semiconductor light emitting diode, a laser diode (LD), or a resonant cavity light emitting diode (RCLED). The down conversion material includes one of phosphor or other material for absorbing light in one spectral region and emitting light in another spectral region. The optic device, or lens, includes light transmissive material.

High Efficiency Light Source Using Solid-State Emitter and Down-Conversion Material

A light emitting apparatus having a light source for emitting short wavelength radiation and an optic device configured to receive the radiation emitted from the light source. A device directs at least some of the short wavelength radiation emitted from the light source into the optic device and a down conversion material receives at least some of the short wavelength radiation directed into the optic device in one spectral region and emits the radiation in another spectral region.

Yimin Gu

Papers

Solid-state lighting: failure analysis of white LEDs

High-power white LEDs and manufacturing method thereof

A noncontact method for determining junction temperature of phosphor-converted white LEDs

High Efficiency Light Source Using Solid-State Emitter and Down-Conversion Material

High-efficient light engines using light emitting diodes