Showing papers by "Yu. N. Ogibin published in 1999"
TL;DR: The electrolysis of 2-oxa-and 2-5-dioxabicycloalkanes involves electrochemical cleavage of the bridging carbon-carbon bonds followed by electrooxidative transformation into methyl ω-(2methoxytetrahydrofuryl)-, ω(dimethoxy-methyl)-, and ω-1,3dioxolan-2-yl)alkanoates as discussed by the authors.
Abstract: Electrolysis of 2-oxa- and 2,5-dioxabicyclo[n.4.0]alk-1(6)0enes (n=4, 10) under conditions of direct undivided anodic oxidation in methanol results in their electrochemical mono-and dimethoxylation; electrolysis of the corresponding 2-oxa-and 2,5-dioxabicycloalkanes involves electrochemical cleavage of the bridging carbon—carbon bonds followed by electrooxidative transformation into methyl ω-(2-methoxytetrahydrofuryl)-, ω-(dimethoxy-methyl)-, and ω-(1,3-dioxolan-2-yl)alkanoates.
4 citations