Recent development of polymer electrolyte membranes for fuel cells.

High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC) – A review

https://cronfa.swan.ac.uk/Record/cronfa48864/Download/0048864-07032019141310.pdf

Reverse osmosis desalination: A state-of-the-art review

The scientific community is focused on the development of inexpensive and high-performing membrane materials for proton exchange membrane (PEM) fuel cells (FCs). The major approach to reducing the cost of FCs, which is crucial for the widespread acceptance of FCs as energy sources for various practical applications, is reducing the cost of the membrane. Efforts are being made in the development of advanced polymeric materials, which will satisfy the technical and economic demands of the consumers. Because most alternative membranes are outperformed by Nafion membranes over an entire set of important properties, it may be worthwhile to compromise on certain parameters to develop alternative specialized membranes. This review presents the properties (mainly conductivity and chemical and mechanical stability) of modern solid polymer electrolytes (SPEs) for PEM FCs.

Review of Advanced Materials for Proton Exchange Membrane Fuel Cells

A comprehensive review on anti-fouling nanocomposite membranes for pressure driven membrane separation processes

The porous structure of the fully-aromatic polyamide film in reverse osmosis membranes

The morphology of fully-aromatic polyamide separation layer and its relationship with separation performance of TFC membranes

Cross-linked polybenzimidazole membranes were obtained by heating at 160 °C, using 4,4′-diglycidyl(3,3′,5,5′-tetramethylbiphenyl) epoxy resin (TMBP) as the cross-linker. The cross-linking reaction temperature was determined by DSC and the successful completion of the cross-linking reaction was shown by FTIR and solubility tests. The cross-linked membranes showed high proton conductivity and strong mechanical properties, as well as low swelling after immersion in 85% phosphoric acid at 90 °C. For instance, the membrane with a cross-linker content weight percent of 20% (PBI-TMBP 20%) with a PA doping level of 4.1 exhibited a proton conductivity of 0.010 S cm−1 and a low swelling volume of 50%. Moreover, the cross-linked membranes showed excellent oxidative stability. The PBI-TMBP 20% cross-linked membrane tested in Fenton's reagent (3% H2O2 solution, 4 ppm Fe2+, 70 °C) kept its shape for more than 480 h and did not break. In particular, the proton conductivity of the PA-PBI-TMBP 20% membrane after Fenton's test (30% H2O2, 20 ppm Fe2+, 85 °C) remained at a high level of 0.009 S cm−1. This investigation proved that cross-linking is a very effective approach for improving the performance of proton exchange membranes.

Zhang Yang

Papers

The porous structure of the fully-aromatic polyamide film in reverse osmosis membranes

The morphology of fully-aromatic polyamide separation layer and its relationship with separation performance of TFC membranes

Cross-linked polybenzimidazole with enhanced stability for high temperature proton exchange membrane fuel cells

Novel epoxy-based cross-linked polybenzimidazole for high temperature proton exchange membrane fuel cells

Novel self-crosslinked poly(aryl ether sulfone) for high alkaline stable and fuel resistant alkaline anion exchange membranes.