Electrochemical sensors play a significant role in detecting chemical ions, molecules, and pathogens in water and other applications. These sensors are sensitive, portable, fast, inexpensive, and suitable for online and in-situ measurements compared to other methods. They can provide the detection for any compound that can undergo certain transformations within a potential window. It enables applications in multiple ion detection, mainly since these sensors are primarily non-specific. In this paper, we provide a survey of electrochemical sensors for the detection of water contaminants, i.e., pesticides, nitrate, nitrite, phosphorus, water hardeners, disinfectant, and other emergent contaminants (phenol, estrogen, gallic acid etc.). We focus on the influence of surface modification of the working electrodes by carbon nanomaterials, metallic nanostructures, imprinted polymers and evaluate the corresponding sensing performance. Especially for pesticides, which are challenging and need special care, we highlight biosensors, such as enzymatic sensors, immunobiosensor, aptasensors, and biomimetic sensors. We discuss the sensors' overall performance, especially concerning real-sample performance and the capability for actual field application.

https://www.mdpi.com/1424-8220/21/12/4131/pdf

A Review of Nanocomposite-Modified Electrochemical Sensors for Water Quality Monitoring.

Electrospun nanofibers have been exploited in multidisciplinary fields with numerous applications for decades. Owing to their interconnected ultrafine fibrous structure, high surface-to-volume ratio, tortuosity, permeability, and miniaturization ability along with the benefits of their lightweight, porous nanofibrous structure, they have been extensively utilized in various research fields for decades. Electrospun nanofiber technologies have paved unprecedented advancements with new innovations and discoveries in several fields of application including energy devices and biomedical and environmental appliances. This review article focused on providing a comprehensive overview related to the recent advancements in health care and energy devices while emphasizing on the importance and uniqueness of utilizing nanofibers. A brief description regarding the effect of electrospinning techniques, setup modifications, and parameters optimization on the nanofiber morphology was also provided. The article is concluded with a short discussion on current research challenges and future perspectives.

A Review on Electrospun Nanofibers Based Advanced Applications: From Health Care to Energy Devices.

Nafion-stabilized black phosphorus nanosheets-maltosyl-β-cyclodextrin as a chiral sensor for tryptophan enantiomers

Applications of carbon-based conductive nanomaterials in biosensors

Electrochemical devices convert chemical reactions into electrical energy or, vice versa, electricity into a chemical reaction. While batteries, fuel cells, supercapacitors, solar cells, and sensors belong to the galvanic cells based on the first reaction, electrolytic cells are based on the reversed process and used to decompose chemical compounds by electrolysis. Especially fuel cells, using an electrochemical reaction of hydrogen with an oxidizing agent to produce electricity, and electrolytic cells, e.g., used to split water into hydrogen and oxygen, are of high interest in the ongoing search for production and storage of renewable energies. This review sheds light on recent developments in the area of electrospun electrochemical devices, new materials, techniques, and applications. Starting with a brief introduction into electrospinning, recent research dealing with electrolytic cells, batteries, fuel cells, supercapacitors, electrochemical solar cells, and electrochemical sensors is presented. The paper concentrates on the advantages of electrospun nanofiber mats for these applications which are mostly based on their high specific surface area and the possibility to tailor morphology and material properties during the spinning and post-treatment processes. It is shown that several research areas dealing with electrospun parts of electrochemical devices have already reached a broad state-of-the-art, while other research areas have large space for future investigations.

https://www.mdpi.com/2073-4360/13/11/1741/pdf

Zhiqiang Ling

Papers

Synthesis and utilization of Co3O4 doped carbon nanofiber for fabrication of hemoglobin-based electrochemical sensor.