Showing papers by "Zygmunt Kazimierczuk published in 1997"
TL;DR: In this paper, the anodic oxidative decarboxylation of isomers of uracil and thymine acetic acids was studied, and the results showed that in acetic acid/sodium acetate medium, these were trapped by acetate, resulting in corresponding acetoxymethyl derivatives.
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TL;DR: In this paper, the anodic oxidative decarboxylation of isomers of uracil and thymine acetic acids was studied, and the results showed that in acetic acid/sodium acetate medium, these were trapped by acetate, resulting in corresponding acetoxymethyl derivatives.
Abstract: The anodic oxidative decarboxylation of isomers of uracil and thymine acetic acids was studied. Electrolysis in methanolic or ethanolic solutions yielded respective alkoxymethyl derivatives via carbocationic intermediates. In acetic acid/sodium acetate medium, these were trapped by acetate, resulting in corresponding acetoxymethyl derivatives. Electrolysis in fully deuterated methanol or deuterated acetic acid, allow to obtain respective trideuterated compounds.