Showing papers in "Appita Journal in 2019"
Journal Article•
TL;DR: In this article, a factorial experiment was conducted to investigate the effect of process variables such as pH, soluble calcium, temperature, dissolved organic material on the colloidal stability of wood extractives.
Abstract: This paper presents the results of regression modelling undertaken to investigate the factors affecting colloidal stability of wood extractives from Pinus radiata. A factorial experiment was conducted to investigate the effect of process variables such as pH, soluble calcium, temperature, dissolved organic material on the colloidal stability of wood extractives at two different levels of wood extractives representative of the maximum and minimum levels in P.radiata extractives. Modelling of the total extractives resulted in poor predictive models. Modelling of the individual wood extracts was found to be more reliable with two way and three way interactions occurring between the process variables. Competing interactions between the process variables and the components were evident.
3 citations
Journal Article•
TL;DR: In this paper, the authors investigated the effect of various key factors that have been identified to affect wood extractive colloid stability and pitch deposition of wood extractives released in thermomechanical pulp of Pinus radiata.
Abstract: This paper presents the results of a study undertaken to investigate the interaction between the various key factors that have been identified to affect wood extractive colloid stability and pitch deposition of wood extractives released in thermomechanical pulp of Pinus radiata. These key factors are temperature, soluble calcium, pH, dissolved carbohydrates and wood extractive concentration and composition. Very little work has been undertaken to study the effect of composition and seasonal changes in Pinus radiata wood extractives on their colloidal stability and pitch deposition. Two different compositions of the wood extractives, representing the maximum and minimum in ester to acid ratio (EAR) that occur during the summer and winter periods, were investigated. The EAR of the extracts was found to significantly affect the wood extract colloidal properties. Low EAR (EAR = 0.31) extracts, typical of the summer period, were found to be more unstable and more susceptible to deposition and destabilisation by soluble calcium than higher EAR (EAR = 0.66) extracts, typical of the winter period. Complex interactions between the various process variables were found. In particular, the dissolved organic matter (DOM) level was found to cause both stabilisation and destabilisation depending on the concentration and the pH. This was more apparent in the higher EAR extract.
3 citations