Showing papers in "Geology in 2022"
TL;DR: In this paper , a compilation of whole-rock geochemical data for tungsten and tin-related granites in major W-sn metallogenic belts is presented, showing that the Sn-related girders are generally the products of higher-temperature partial melting (~800 °C) than the W-related ones.
Abstract: Abstract Most tungsten (W) and tin (Sn) deposits are associated with highly evolved granites derived from the anatexis of metasedimentary rocks. They are commonly separated in both space and time, and in the rare cases where the W and Sn mineralization are part of a single deposit, the two metals are temporally separate. The factors controlling this behavior, however, are not well understood. Our compilation of whole-rock geochemical data for W- and Sn-related granites in major W-Sn metallogenic belts shows that the Sn-related granites are generally the products of higher-temperature partial melting (~800 °C) than the W-related granites (~750 °C). Thermodynamic modeling of partial melting and metal partitioning shows that W is incorporated into the magma formed during low-temperature muscovite-dehydration melting, whereas most of the Sn is released into the magma at a higher temperature during biotite-dehydration melting; the Sn of the magma may be increased significantly if melt is extracted prior to biotite melting. At the same degree of partial melting, the concentrations of the two metals in the partial melt are controlled by their concentration in the protolith. Thus, the nature of the protolith and the melting temperature and subsequent evolution of the magma all influence the metallogenic potential of a magma and, in combination, helped control the spatial and temporal segregation of W and Sn deposits in all major W-Sn metallogenic belts.
32 citations
TL;DR: In this article , high-resolution biomarker and compound-specific isotope distributions coupled with degradation of calcareous fossil remnants reveal that intensive euxinia and decalcification (acidification) driven by Central Atlantic magmatic province (CAMP) activity formed a two-pronged kill mechanism at the end-Triassic mass extinction.
Abstract: High-resolution biomarker and compound-specific isotope distributions coupled with the degradation of calcareous fossil remnants reveal that intensive euxinia and decalcification (acidification) driven by Central Atlantic magmatic province (CAMP) activity formed a two-pronged kill mechanism at the end-Triassic mass extinction. In a newly proposed extinction interval for the basal Blue Lias Formation (Bristol Channel Basin, UK), biomarker distributions reveal an episode of persistent photic zone euxinia (PZE) that extended further upward into the surface waters. In the same interval, shelly taxa almost completely disappear. Beginning in the basal paper shales of the Blue Lias Formation, a Lilliput assemblage is preserved consisting of only rare calcitic oysters (Liostrea) and ghost fossils of decalcified aragonitic bivalves. The stressors of PZE and decalcification parsimoniously explain the extinction event and inform possible combined causes of other biotic crises linked to emplacement of large igneous provinces, notably the end-Permian mass extinction, when PZE occurred on a broad and perhaps global scale.
24 citations
TL;DR: The Emeishan large igneous province (LIP) is thought to have been a potential driver for the biotic crises and paleoclimate changes around the Guadalupian-Lopingian boundary (GLB; Permian), but the lack of high-precision radiometric dates to constrain the duration and eruption rates of the volcanism has limited the assessment of their relationship as discussed by the authors .
Abstract: The Emeishan large igneous province (LIP), southwestern China and northern Vietnam, is thought to have been a potential driver for the biotic crises and paleoclimate changes around the Guadalupian-Lopingian boundary (GLB; Permian), but the lack of high-precision radiometric dates to constrain the duration and eruption rates of the volcanism has limited the assessment of their relationship. We present new chemical abrasion–isotope dilution–isotope ratio mass spectrometry U-Pb zircon geochronology of three samples from the lowermost and uppermost parts of the volcanic succession in the central portion of the Emeishan LIP. The results demonstrate that Emeishan volcanism began by 260.55 ± 0.07 Ma and persisted until at least 257.22 ± 0.37 Ma. Combined with a previously published age of 259.1 ± 0.5 Ma for silicic ignimbrites, we estimate that ~85% of Emeishan LIP volume erupted within 1.45 ± 0.50 m.y. Our new results confirm that the Emeishan volcanism began slightly prior to the initiation of the associated mass extinction event and was contemporaneous with the associated warming interval. The new data support the hypothesis that the Emeishan LIP likely triggered the biotic crises and paleoclimate changes around the GLB.
18 citations
TL;DR: In this article , the late Permian and early Triassic atmospheric CO2 history was reconstructed by applying the paleosol pCO2 barometer, showing an approximate 4× increase from mean concentrations of 412-919 ppmv in the late Changhsingian to maximum levels between 2181 and 2610 ppmv.
Abstract: The end-Permian mass extinction, the largest biological crisis in Earth history, is currently understood in the context of Siberian Traps volcanism introducing large quantities of greenhouse gases to the atmosphere, culminating in the Early Triassic hothouse. In our study, the late Permian and Early Triassic atmospheric CO2 history was reconstructed by applying the paleosol pCO2 barometer. Atmospheric pCO2 shows an approximate 4× increase from mean concentrations of 412–919 ppmv in the late Permian (Changhsingian) to maximum levels between 2181 and 2610 ppmv in the Early Triassic (late Griesbachian). Mean CO2 estimates for the later Early Triassic are between 1261–1936 ppmv (Dienerian) and 1063–1757 ppmv (Spathian). Significantly lower concentrations ranging from 343 to 634 ppmv are reconstructed for the latest Early to Middle Triassic (Anisian). The 5 m.y. episode of elevated pCO2 suggests that negative feedback mechanisms such as silicate weathering were not effective enough to reduce atmospheric pCO2 to precrisis levels and that marine authigenic clay formation (i.e., reverse weathering) may have been an important component of the global carbon cycle keeping atmospheric pCO2 at elevated levels.
17 citations
TL;DR: In this article , the first discovery of early Paleozoic boninitic blueschists and associated greenschists from the eastern Proto-Tethyan North Qilian orogenic belt, northeastern Tibet, which have geochemical affinities that are typical of forearc boninites and island arc basalts, were reported.
Abstract: Abstract Subduction of oceanic lithosphere is a diagnostic characteristic of plate tectonics. However, the geodynamic processes from initiation to termination of subduction zones remain enigmatic mainly due to the scarcity of appropriate rock records. We report the first discovery of early Paleozoic boninitic blueschists and associated greenschists from the eastern Proto-Tethyan North Qilian orogenic belt, northeastern Tibet, which have geochemical affinities that are typical of forearc boninites and island arc basalts, respectively. The boninitic protoliths of the blueschists record intra-oceanic subduction initiation at ca. 492–488 Ma in the eastern North Qilian arc/forearc–backarc system, whereas peak blueschist facies metamorphism reflects subsequent subduction of the arc/forearc complex to high pressure at ca. 455 Ma. These relations therefore record the life circle of an intra-oceanic subduction zone within the northeastern Proto-Tethys Ocean. The geodynamic evolution provides an early Paleozoic analogue of the early development of the Izu–Bonin–Mariana arc and its later subduction beneath the extant Japanese arc margin. This finding highlights the important role of subduction of former upper plate island arc/forearcs in reducing the likelihood of preservation of initial subduction-related rock records in ancient orogenic belts.
14 citations
TL;DR: In this article , the retroarc positions of the Andean topographic front and foreland deformation front range from 300 to 900 km inboard of the trench axis, and the spatial correspondence of retroarc shortening with specific geodynamic configurations demonstrates the mechanical role of flat slab subduction, slab window development, and combined structural and stratigraphic geometries in shaping the orogenic architecture of Cordilleran margins.
Abstract: Convergent plate boundaries show sharp variations in orogenic width and extent of intraplate deformation. Analysis of late Cenozoic contractile deformation along the Andean mountain front and adjacent foreland highlights the contrasting degrees of deformation advance toward the plate interior. The retroarc positions of the Andean topographic front (marked by frontal thrust-belt structures) and foreland deformation front (defined by isolated basement block uplifts) range from 300 to 900 km inboard of the trench axis. Over the ~8000 km arcuate length of the Andes (10°N to 55°S), four discrete maxima of inboard deformation advance are spatially co-located with the Peruvian (5°S–14°S) and Pampean (27°S–33°S) zones of flat slab subduction, the subducted Chile Ridge (45°S–48°S), and the anomalously thick Paleozoic stratigraphic wedge of Bolivia (17°S–23°S). The spatial correspondence of retroarc shortening with specific geodynamic configurations demonstrates the mechanical role of flat slab subduction, slab window development, and combined structural and stratigraphic geometries in shaping the orogenic architecture of Cordilleran margins, largely through lithospheric strengthening, weakening, and/or tectonic inheritance.
14 citations
TL;DR: In this paper , the authors compared time averaging across five phyla of major carbonate producers co-occurring in a sediment core from the northern Adriatic Sea shelf, and found that despite different skeletal architecture, mineralogy, and life habit, all taxa showed very similar time averaging varying from ~1800 to ~3600 yr.
Abstract: Time averaging of fossil assemblages determines temporal precision of paleoecological and geochronological inferences. Taxonomic differences in intrinsic skeletal durability are expected to produce temporal mismatch between co-occurring species, but the importance of this effect is difficult to assess due to lack of direct estimates of time averaging for many higher taxa. Moreover, burial below the taphonomic active zone and early diagenetic processes may alleviate taxonomic differences in disintegration rates in subsurface sediments. We compared time averaging across five phyla of major carbonate producers co-occurring in a sediment core from the northern Adriatic Sea shelf. We dated individual bivalve shells, foraminiferal tests, tests and isolated plates of irregular and regular echinoids, crab claws, and fish otoliths. In spite of different skeletal architecture, mineralogy, and life habit, all taxa showed very similar time averaging varying from ~1800 to ~3600 yr (interquartile age ranges). Thus, remains of echinoids and crustaceans—two groups with multi-elemental skeletons assumed to have low preservation potential—can still undergo extensive age mixing comparable to that of the co-occurring mollusk shells. The median ages of taxa differed by as much as ~3700 yr, reflecting species-specific timing of seafloor colonization during the Holocene transgression. Our results are congruent with sequestration models invoking taphonomic processes that minimize durability differences among taxa. These processes together with temporal variability in skeletal production can overrule the effects of durability in determining temporal resolution of multi-taxic fossil assemblages.
13 citations
TL;DR: In this article , molybdenum, uranium, cadmium, and zinc stable-isotope data from two stratigraphic successions of the same Lower Jurassic Posidonienschiefer unit in the Lower Saxony Basin of northern Germany were affected by different burial histories.
Abstract: Abstract The isotope ratios of redox-sensitive metals in organic-rich rocks are critical tools for quantifying the timing and severity of deoxygenation and nutrient cycling in Earth's past. The resilience of isotopic data to thermal alteration of the host sediments over millions of years of burial is, however, largely unknown. We present molybdenum, uranium, cadmium, and zinc stable-isotope data from two stratigraphic successions of the same Lower Jurassic Posidonienschiefer unit in the Lower Saxony Basin of northern Germany that were affected by different burial histories. We show that thermal maturity had no effect on the isotopic compositions of these elements but does appear to have increased their concentrations in the rock. The data corroborate the results of laboratory-based maturation studies and provide constraints on the Mo, U, Cd, and Zn isotopic compositions of ca. 182 Ma seawater in the Lower Saxony Basin.
13 citations
TL;DR: In this article , the authors presented the first extensive in situ laser ablation-inductively coupled plasma-mass spectrometry element data set collected from metasediment-hosted muscovite and biotite from three different metamorphic cross sections traversing sub-greenschist-to-granulite-facies conditions.
Abstract: Metals such as Li, Be, V, Co, Nb, In, Cs, Sn, Ta, and W are considered resources that are critical for modern economies. They can be significantly enriched in granites and pegmatites, but the mechanisms of enrichment remain poorly understood. Many metal-enriched granitic magmas form through mica dehydration reactions during high-grade metamorphism. The preferential incorporation of these metals into micas provides a mechanism for concentration and mobilization during crustal melting. Comprehensive data sets of these elements and their partitioning in metamorphic micas across different metamorphic grades are currently lacking. We present the first extensive in situ laser ablation–inductively coupled plasma–mass spectrometry element data set collected from metasediment-hosted muscovite and biotite from three different metamorphic cross sections traversing sub-greenschist- (~400 °C) to granulite-facies conditions (>900 °C). Within the same sample, Li, V, Co, Cs, and Ta concentrations are higher in biotite, whereas Be, In, Sn, and W concentrations are higher in muscovite. Subsolidus micas record only nonsystematic compositional variations between samples. Suprasolidus biotites show systematic depletion in Li, Be, Sn, and Cs and enrichment in V and Co with increasing temperature in the highest-grade (muscovite-absent) samples. Indium and W reach peak concentrations in biotite at 750 °C and 850 °C, respectively. Muscovites record systematic enrichment in In and W and depletion in Be, Sn, and Cs with increasing metamorphic grade. These distinctive trends appear to be independent of tectonic setting (i.e., continental collision and crustal thinning). Our data set highlights the importance of higher-temperature melting (>750 °C), in particular, biotite breakdown reactions, for the release of Li, Be, Sn, Cs, and W into crustal melts.
13 citations
TL;DR: In this paper , the authors quantitatively constrain secondary oil migration processes under an absolute time frame by integrating oil-inclusion fluorescence and in situ calcite U-Pb dating on calcite veins and cements hosting primary oil inclusions.
Abstract: Abstract Tracing secondary oil migration pathways is critical for understanding petroleum system evolution histories. Traditional tools (e.g., molecular indicators and numerical modeling) utilized for evaluating oil migration processes either lead to ambiguous interpretations or only provide qualitative estimates. We quantitatively constrain secondary oil migration processes under an absolute time frame by integrating oil-inclusion fluorescence and in situ calcite U-Pb dating on calcite veins and cements hosting primary oil inclusions. Fluorescence spectra of oil inclusions and U-Pb ages were obtained on samples from ultra-deep Ordovician reservoirs along two major faults in the Halahatang oilfield, Tarim Basin (northwestern China). Absolute U-Pb ages suggest two main oil charge events during 475–433 Ma and 294–262 Ma, respectively, and revealed a northward-decreasing trend for oil maturity during single charge events. Vertical migration of oil from in situ source rock through active (or reactivated) faults is believed to be the key process inducing the spatial maturity variation in charged oils and considered as the main mechanism of secondary migration, with brecciated fault zones and dilatant fractures along faults acting as major vertical oil-migration pathways. The successful application of this approach has wider implications for elucidating petroleum migration processes in tectonic complex basins worldwide.
12 citations
TL;DR: In this article , a study of crustal xenoliths and zircon xenocrysts in 6.0-2.3 Ma lavas in the Qiangtang Block was conducted and the results suggest that the early Miocene cold-hot thermal transition of the middle-lower crust was near-synchronous with topographic evolution from high-relief mountains to a flat plateau, which supports crustal flow as the main topographic smoothing mechanism for central-northern Tibet.
Abstract: Abstract The topographic transition of central–northern Tibet since the early Miocene has created a consistently high and flat plateau similar to that of today. However, to date, the associated deep crust and/or /mantle events are poorly understood, mainly due to an early Miocene metamorphic–magmatic lull within the Qiangtang Block. To address this issue, we undertook a study of crustal xenoliths and zircon xenocrysts in 6.0–2.3 Ma lavas in the Qiangtang Block. The occurrence of 22.6–12.9 Ma high-temperature–low-pressure granulite xenoliths implies that the middle crust of the block has been very hot since that time. Zircon xenocrysts and granitic xenoliths from 6.0–2.3 Ma lavas were studied and shown to have high δ18O values, which supports Miocene crustal melting and the formation of unexposed, coeval felsic plutons. Combined with paleoelevation data from the Tibetan Plateau, our results suggest that the early Miocene cold–hot thermal transition of the middle–lower crust was near-synchronous with topographic evolution from high-relief mountains to a flat plateau, which supports crustal flow as the main topographic smoothing mechanism for central–northern Tibet.
TL;DR: Analytical methods and data as discussed by the authors were used in the analysis of this paper. But they were not used in this paper's analysis of as discussed by the authors . But they did not use them in this article.
Abstract: Analytical methods and data.
TL;DR: In this article , primary fluid inclusions in bedded halite from the 830m.y.-old Browne Formation of central Australia contain organic solids and liquids, as documented with transmitted light and ultraviolet-visible (UV-vis) petrography.
Abstract: Primary fluid inclusions in bedded halite from the 830-m.y.-old Browne Formation of central Australia contain organic solids and liquids, as documented with transmitted light and ultraviolet–visible (UV-vis) petrography. These objects are consistent in size, shape, and fluorescent response with cells of prokaryotes and eukaryotes and with organic compounds. This discovery shows that microorganisms from saline depositional environments can remain well preserved in halite for hundreds of millions of years and can be detected in situ with optical methods alone. This study has implications for the search for life in both terrestrial and extraterrestrial chemical sedimentary rocks.
TL;DR: In this article , in situ measurements of lithium isotopes in garnet reveal evidence of episodic fluid transport in a subduction shear zone now exposed in the Monviso ophiolite (Western Alps).
Abstract: Episodic fluid overpressure and escape is invoked as a cause or consequence of many subduction-zone seismic phenomena but can be challenging to constrain in exhumed high-pressure metamorphic rocks. In situ measurements of lithium isotopes in garnet reveal evidence of episodic fluid transport in a subduction shear zone now exposed in the Monviso ophiolite (Western Alps). Garnet from an eclogite block and associated metasomatic reaction rind was analyzed by secondary ion mass spectrometry (SIMS). All analyzed garnet preserves core-rim zoning in δ7Li and large negative δ7Li excursions (NEs) in mantles. These excursions cannot be explained by instrumental mass fractionation during analysis, equilibrium fractionation, or intracrystalline diffusion of Li within garnet. Instead, NEs were produced by kinetic fractionation of Li isotopes during bulk diffusion through a pore fluid, and the fractionated isotopic compositions were incorporated into garnet by syn-diffusion growth. Disequilibrium garnet growth textures associated with negative δ7Li support this interpretation and suggest metasomatism drove rapid garnet growth. Four distinct NEs were identified requiring that at least four pulses of fluid were transported within the adjacent shear zone. This evidence of episodic fluid transport along a subduction shear zone at eclogite facies supports models of intermediate-depth seismicity that rely on cyclic fluid overpressure and escape.
TL;DR: In this paper , the fine structure and thermal state of the continental lithospheric mantle (CLM) in the Siberian craton were investigated using petrographic, in situ chemical, and P-T data for 92 new garnet peridotite xenoliths from the Udachnaya kimberlite.
Abstract: Abstract The fine structure and thermal state of >200-km-thick cratonic lithosphere remain poorly explored because of insufficient sampling and uncertainties in pressure (P) and temperature (T) estimates. We report exceptionally detailed thermal and compositional profiles of the continental lithospheric mantle (CLM) in the Siberian craton based on petrographic, in situ chemical, and P-T data for 92 new garnet peridotite xenoliths from the Udachnaya kimberlite, as well as literature data. The thermal profile is complex, with samples indicating model conductive geotherms between 40 and 35 mW/m2 at ~55–130 km, colder (35 mW/m2 geotherm) mantle from 140 to 190 km, and hotter layers at the CLM base (190–230 km) and at ~135 km. The latter, previously unidentified, anomalous midlithospheric horizon has rocks up to 150 °C hotter than the 35 mW/m2 geotherm, that are rich in garnet and clinopyroxene, have low Mg#, and have melt-equilibrated rare earth element patterns. We posit that this horizon formed in a depth range where ascending melts stall (e.g., via loss of volatiles and redox change), heat wall-rock harzburgites, and transform them to lherzolites or wehrlites. This may explain some seismic midlithosphere discontinuities (MLDs) in cratons. By contrast, we found no rocks rich in metasomatic volatile-rich amphibole, phlogopite, or carbonate matching the MLD, nor layers composed of peridotites with distinct melt-extraction degrees. The CLM below 190 km contains both coarse and variably deformed rocks heated and reworked (Mg#Ol down to 0.86) by localized lithosphere-asthenosphere interaction.
TL;DR: In this article , the authors integrated microstructural, U-Pb, and geochemical analyses of apatite grains from an exhumed mylonitic shear zone in the St. Barthélémy Massif, Pyrenees, France, to understand how deformation and metasomatism are recorded by UPb dates.
Abstract: The timing and processes of ductile deformation and metasomatism can be documented using apatite petrochronology. We integrated microstructural, U-Pb, and geochemical analyses of apatite grains from an exhumed mylonitic shear zone in the St. Barthélémy Massif, Pyrenees, France, to understand how deformation and metasomatism are recorded by U-Pb dates and geochemical patterns. Electron backscatter diffraction (EBSD) analyses documents crystal plastic deformation characterized by low-angle boundaries (<5°) associated with dislocation creep and evidence of multiple slip systems. Laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) U-Pb maps indicate that dates in deformed grains reflect, and are governed by, low-angle dislocation boundaries. Apatite rare earth element (REE) and U-Pb behavior is decoupled in high-grade gneiss samples, suggesting REEs record higher-temperature processes than U-Pb isotopic systems. Apatite from (ultra)mylonitic portions of the shear zone showed evidence of metasomatism, and the youngest dates constrain the age of metasomatism. Collectively, these results demonstrate that crystal plastic microstructures and fluid interactions can markedly change apatite isotopic signatures, making single-grain apatite petrochronology a powerful tool for dating and characterizing the latest major deformation and/or fluid events, which are often not captured by higher-temperature chronometers.
TL;DR: In this paper , the authors reconstructed the evolution of ore-forming fluids using hydrothermal quartz from the 17.4 Ma Zhibula skarn, Tibet, and inferred two pulses of metalliferous fluids and a meteoric water incursion event.
Abstract: Abstract Quantifying the rhythms and rates of magmatic-hydrothermal systems is critical for a better understanding of their controls on ore formation and the dynamics of magmatic reservoirs that feed them. We reconstructed the evolution of ore-forming fluids using hydrothermal quartz from the 17.4 Ma Zhibula skarn, Tibet. Ion probe analysis reveals sharp and dramatic changes in quartz δ18O values between 5‰ and −9.3‰, with fluid δ18O values varying between 2.8‰ and −18.2‰, which are best explained by transient meteoric water incursion into a hydrothermal system dominated by magmatic fluids. Two pulses of magmatic fluids and a meteoric water incursion event are inferred, which operated at the millennium scale (760−1510 yr) as constrained by the aluminum diffusion chronometer. Our results indicate that magmatic reservoirs are likely water unsaturated for most of their lifetime (>105−106 yr), with transient and episodic fluid exsolutions (~103 yr) being driven by magma replenishment or crystallization-induced water saturation. With focused and efficient metal deposition, multiple pulses of metalliferous fluids favor the formation of giant deposits with high grade. Meteoric water δ18O values (−25.4 ± 2.3‰) derived from Zhibula quartz further suggest a paleo-elevation of 5.9 ± 0.3 km; this transient early Miocene surface uplift plausibly was due to break-off of the oceanic slab attached to the Indian Plate. Our research highlights that ubiquitous hydrothermal quartz in orogenic belts can probe the dynamics of magmatic-hydrothermal systems and also quantify paleo-elevations, which has significant tectonic implications.
TL;DR: In this paper , a petrographic-guided rhenium-osmium (Re-Os) organic-bearing sedimentary unit study on the Lantian biota was performed and the results indicated that the differentiation and radiation of macroscopic eukaryotes, and the evolution of the primitive, erect epibenthic ecosystem, occurred in the early-mid Ediacaran and were associated with highly fluctuating oceanic redox conditions.
Abstract: Abstract The morphologically differentiated benthic macrofossils of algae and putative animal affinities of the Lantian biota in China represents the oldest known Ediacaran macroscopic eukaryotic assemblage. Although the biota provides remarkable insights into the early evolution of complex macroeukaryotes in the Ediacaran, the uncertainty in its age has hampered any robust biological evaluation. We resolve this issue by applying a petrographic-guided rhenium-osmium (Re-Os) organic-bearing sedimentary unit study on the Lantian biota. This work confines a minimum age for the first appearance of the Lantian biota to 602 ± 7 Ma (2σ, including decay constant uncertainty). This new Re-Os date confirms that the Lantian biota is of early–mid Ediacaran age and temporally distinct from the typical Ediacaran macrobiotas. Our results indicate that the differentiation and radiation of macroscopic eukaryotes, and the evolution of the primitive, erect epibenthic ecosystem, occurred in the early–mid Ediacaran and were associated with highly fluctuating oceanic redox conditions. The radiogenic initial 187Os/188Os ratios derived from the Lantian (1.14 ± 0.02) and other Ediacaran shales invoke oxidative weathering of upper continental crust in the early–middle Ediacaran, which may have stimulated the evolution of life and oceanic-atmospheric oxygenation. Integrated with published Ediacaran chronological and geochemical data, our new Re-Os geochemical study of the Lantian black shale provides a refined, time-calibrated record of environment and eukaryote evolution during the Ediacaran.
TL;DR: In this paper , the authors presented new high-resolution planktic foraminiferal, geochemical, and geophysical data from the Zumaia section (Spain), calibrated to an updated orbitally tuned age model.
Abstract: Abstract Untangling the timing of the environmental effects of Deccan volcanism with respect to the Chicxulub impact is instrumental to fully assessing the contributions of both to climate change over the Cretaceous-Paleogene boundary (KPB) interval. Despite recent improvements in radiometric age calibrations, the accuracy of age constraints and correlations is insufficient to resolve the exact mechanisms leading to environmental and climate change in the 1 m.y. across the KPB. We present new high-resolution planktic foraminiferal, geochemical, and geophysical data from the Zumaia section (Spain), calibrated to an updated orbitally tuned age model. We provide a revised chronology for the major carbon isotope excursions (CIEs) and planktic foraminiferal events and test temporal relationships with different models of the eruptive phases of the Deccan Traps. Our data show that the major CIEs near the KPB, i.e., the late Maastrichtian warming event (66.25–66.10 Ma) and the Dan-C2 event (65.8–65.7 Ma), are synchronous with the last and the first 405 k.y. eccentricity maximum of the Maastrichtian and the Danian, respectively, and that the minor Lower C29n event (65.48–65.41 Ma) is well constrained to a short eccentricity maximum. Conversely, we obtained evidence of abrupt environmental change likely related to Deccan volcanism at ca. 65.9 Ma, based on a bloom of opportunistic triserial guembelitriids (Chiloguembelitria). The orbital, isotopic, and paleobiological temporal relationships with Deccan volcanism established here provide new insights into the role of Deccan volcanism in climate and environmental change in the 1 m.y. across the KPB.
TL;DR: In this article , Qinling and Taihang mountain ranges were used to study the role of topographic growth in the evolution of the Cenozoic Asian climate system and found that the building of these two mountain ranges around the Oligocene-Miocene boundary temporally and spatially coincided with the reorganization of the Asian climate regime.
Abstract: Abstract The Cenozoic Asian climate system experienced a transformation from a zonal pattern to a monsoon-dominant pattern around the Paleogene-Neogene boundary. A series of dynamic mechanisms, such as uplift of the Tibetan Plateau, retreat of the Paratethys Sea, expansion of the South China Sea, and decreasing atmospheric CO2 content, has been suggested to be responsible for the transformation of the Asian climate pattern. However, the role of topographic growth in eastern China has been rarely considered. As the natural divides of geography, climate, and biology, the two most distinct sets of topographic relief in eastern China, the Qinling and Taihang Mountains, play an important role in shaping the Asian climate pattern. We report low-temperature thermochronology data from the Qinling and Taihang Mountains and use age-elevation relationships and thermal history modeling to show that both mountain ranges experienced a phase of rapid exhumation during the late Oligocene and early Miocene. The building of the Qinling and Taihang Mountains around the Oligocene-Miocene boundary temporally and spatially coincided with the reorganization of the Cenozoic Asian climate regime, suggesting that the mountain building in eastern China acted as a possible driving mechanism for the alleged reorganization of the Cenozoic Asian climate regime.
TL;DR: In this paper , the authors search for feldspathic lithologies in pre-Noachian (older than ca. 4.1 Ga) crustal blocks uplifted by the Hellas basin-forming impact.
Abstract: Due to its size and observable record of ancient rock, Mars is key to understanding crustal formation on planetary bodies, including Venus and Earth, which may have derived their first stable crust from mantle-overturn melting. Recent evidence that ancient martian crust contains an evolved component supports inferences of a pervasive, buried feldspathic component to the crust. With data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), we searched for feldspathic lithologies in pre-Noachian (older than ca. 4.1 Ga) crustal blocks uplifted by the Hellas basin-forming impact. We present evidence for ancient feldspathic rocks exposed across an ~2200 × 600 km area north of Hellas. Given their pre-Noachian age and stratigraphic position directly above putative mantle material, it is possible that these outcrops represent martian primary crust. Our discovery supports the hypothesis that there exists a pervasive, subsurface feldspathic component to the martian crust—a hypothesis that has, until now, been supported only by inferences from geodynamic data and small-scale observations.
TL;DR: In this article , the authors provided an example of Cenozoic cratonic keel delamination in a collisional orogen and highlighted the key roles of compositional and thermal densification in delamination during subduction and collision.
Abstract: It is widely thought that oceanic subduction can trigger cratonic keel delamination, but the southwestern Yangtze craton (SYC; southwestern China) lost its lower keel during Cenozoic continental collision. The upper mantle beneath the thinned SYC contains its incompletely delaminated keel, which has high-velocity seismic anomalies. Combining geophysical observations with the geochemistry of Eocene mafic potassic lavas derived from the SYC mantle at different depths, we suggest that the deep (~130 km) delaminated lithosphere was more fertile and dense, with low-forsterite (Fo; molar 100 × Mg/[Mg + Fe] = 91.3) and high-δ18O (5.9‰) olivine, than the shallow (~55 km) intact lithosphere (Fo = 94.2; δ18O = 5.2‰), although both were rehydrated and oxidized. The deep keel underwent strong refertilization and densification owing to the addition of Fe-rich basaltic melts during earlier oceanic subduction. Subduction-driven refertilization and subsequent collision-driven cooling caused cratonic keel delamination due to compositional and thermal densification rather than hydration- or oxidation-induced rheological weakening. Our study provides an example of Cenozoic cratonic keel delamination in a collisional orogen and highlights the key roles of compositional and thermal densification in delamination during subduction and collision.
TL;DR: In this paper , the elemental relationships, non-detrital metal contents, and raw geochemical data are discussed. But the focus is on the geochemical properties of the raw data.
Abstract: Details of elemental relationships, non-detrital metal contents, and raw geochemical data
TL;DR: In this article , the age and thermobaric ratio (temperature/pressure [T/P]) of metamorphism over the past 2 b.y.y were compared with the inferred plate kinematics with the age.
Abstract: Since the Jurassic, there has been a clear spatiotemporal correlation between different types of metamorphism and active convergent plate margins. However, the extent to which this relationship extends into the past is poorly understood. We compared paleogeographic reconstructions and inferred plate kinematics with the age and thermobaric ratio (temperature/pressure [T/P]) of metamorphism over the past 2 b.y. The null hypothesis—that there is no spatiotemporal link between inferred plate margins and metamorphism—can be rejected. Low-T/P metamorphism is almost exclusively located near plate margins, whereas intermediate- and high-T/P metamorphism skews toward increasingly greater distances from these margins, consistent with three different tectonic settings: the subduction zone, the mountain belt, and the orogenic hinterland, respectively. However, paleogeographic reconstructions suggest that so-called “paired metamorphic belts” are rare and that high- and low-T/P localities more commonly occur along strike from each other. The observation that bimodal metamorphism is largely a function of distance from the trench and that end-member T/P types rarely occur in the same place can be explained if the style of orogenesis has evolved from hotter to colder, consistent with the abrupt emergence of low-T/P metamorphism in the Cryogenian. The widespread development of high-T/P rocks in orogenic hinterlands in the Proterozoic was followed by the production and efficient exhumation of low-T/P rocks in subduction channels in the Phanerozoic.
TL;DR: In this article , the authors exploit a dense array of high-resolution marine seismic reflection profiles to link the marine stratigraphy to onshore volcanic sequences and present the first consistent chronological framework for the CSKVF, enabling a detailed reconstruction of the evolution of the volcanic rift system in time and space.
Abstract: Abstract The Christiana-Santorini-Kolumbo volcanic field (CSKVF) in the Aegean Sea is one of the most active volcano-tectonic lineaments in Europe. Santorini has been an iconic site in volcanology and archaeology since the 19th century, and the onshore volcanic products of Santorini are one of the best-studied volcanic sequences worldwide. However, little is known about the chronology of volcanic activity of the adjacent submarine Kolumbo volcano, and even less is known about the Christiana volcanic island. In this study, we exploit a dense array of high-resolution marine seismic reflection profiles to link the marine stratigraphy to onshore volcanic sequences and present the first consistent chronological framework for the CSKVF, enabling a detailed reconstruction of the evolution of the volcanic rift system in time and space. We identify four main phases of volcanic activity, which initiated in the Pliocene with the formation of the Christiana volcano (phase 1). The formation of the current southwest-northeast–trending rift system (phase 2) was associated with the evolution of two distinct volcanic centers, the newly discovered Poseidon center and the early Kolumbo volcano. Phase 3 saw a period of widespread volcanic activity throughout the entire rift. The ongoing phase 4 is confined to the Santorini caldera and Kolumbo volcano. Our study highlights the fundamental tectonic control on magma emplacement and shows that the CSKVF evolved from a volcanic field with local centers that matured only recently to form the vast Santorini edifice.
Abstract: Potassium-rich adakitic rocks have been used to infer high-pressure (HP) melting of thickened or foundered mafic lower crust in post-collisional settings. However, their origin remains debated because of their potassic rather than sodic nature. We address this debate by investigating the source of post-collisional Oligocene high-K adakitic granites in southern Tibet, which are widely attributed to melting of overthickened mafic lower crust. Our new data provide evidence for the generation of these high-K adakitic granites by anatexis of exposed migmatitic intermediate to felsic arc orthogneisses. These granites contain high-Th/U Oligocene magmatic zircons (30–22 Ma), and inherited zircons (66–48 Ma) with the same εHf(t) (0 to +12) as the coeval migmatites. The migmatites have in turn low-Th/U metamorphic Oligocene zircon rims around 66–48 Ma magmatic zircon cores recording the anatectic event at 29–25 Ma. Phase equilibrium modeling yields an anatectic temperature of ~740 °C and pressure (P) of ~0.9 GPa and shows that garnet is stable at P > 0.7 GPa in the melt-present field. The results indicate that high-K adakitic magmas are derived from melting of older intermediate to felsic arc rocks at intermediate pressures, in the garnet stability field, without any involvement of HP melting of metabasaltic rocks. We propose that hybridization between such purely crustal magmas and subcontinental lithospheric mantle–derived shoshonitic magmas results in the hybridized post-collisional Oligocene–Miocene mafic microgranular enclave–bearing potassic adakitic granitic rocks in southern Tibet.
TL;DR: Analytical methods, Figures S1-S5, and Tables S1−S5 were used in this paper to evaluate the performance of the proposed method, and the results showed promising results.
Abstract: Analytical methods, Figures S1–S5, and Tables S1–S5.
TL;DR: In this article , the authors deconstructed the phreatomagmatic eruption of Taal volcano (Philippines) on 12 January 2020 to investigate the origin of its powerful volcanic thunderstorm.
Abstract: Abstract Advances in global lightning detection have provided novel ways to characterize explosive volcanism. However, researchers are still at the early stages of understanding how volcanic plumes become electrified on different spatial and temporal scales. We deconstructed the phreatomagmatic eruption of Taal volcano (Philippines) on 12 January 2020 to investigate the origin of its powerful volcanic thunderstorm. Satellite analysis indicated that the water-rich plume rose >10 km high before creating lightning detected by Vaisala's global lightning data set (GLD360). Flash rates increased with plume heights and cloud expansion over time, producing >70 flashes min–1. Photographs revealed a highly electrified region at the base of the umbrella cloud, where we infer strong convective updrafts and icy collisions enhanced the electrical activity. These findings inform a conceptual model with overlapping regimes of charge generation in wet eruptions—initially due to ash particle collisions near the vent, followed by thunderstorm-like electrification in icy regions of the upper plume. Despite the wide reach of Taal's ash cloud, most of the lightning occurred within 20–30 km of the volcano, producing thousands of hazardous cloud-to-ground flashes over a densely populated area. The eruption demonstrates that volcanic lightning can pose a hazard in its own right, embedded within the broader hazards of explosive volcanism in an urban setting.
TL;DR: In this article , the authors present a set of analytical procedures, analytical procedures and data tables, along with sample information, analytical procedure, and analytical procedures for the analysis of the data.
Abstract: Sample information, analytical procedures, and data tables.
TL;DR: In this paper , the authors analyzed 80 clinoforms from 10 basins spanning Cenozoic and Mesozoic icehouse, transitional, and greenhouse climate settings and found that greenhouse marine shelves were substantially narrower than icehouse equivalents, suggesting that narrower shelves with persistent shelf-edge deltas were a consequence of lower rates of accommodation change in greenhouse climate intervals that lacked the large ice sheets required to drive high-amplitude highfrequency glacio-eustasy.
Abstract: Abstract Marine shelves are a ubiquitous feature of modern Earth, developed across a wide range of scales in many sedimentary basins and representing the flooded portion of basin-margin clinoform topsets. Analysis of 80 clinoforms from 10 basins spanning Cenozoic and Mesozoic icehouse, transitional, and greenhouse climate settings indicates that normalized mean greenhouse marine shelf width is 33% of normalized mean total measured clinoform topset length. The equivalent value for transitional settings is 43%, and 72% for icehouse marine shelves. These values demonstrate that greenhouse marine shelves were substantially narrower than icehouse equivalents, suggesting that narrower shelves with persistent shelf-edge deltas were a consequence of lower rates of accommodation change in greenhouse climate intervals that lacked the large ice sheets required to drive high-amplitude high-frequency glacio-eustasy. Because greenhouse climates have been the dominant mode through Earth history, narrow shelves have probably been the dominant form, and conceptual models based on modern relatively wide shelves may be poor predictors of paleogeography, sediment routing, and sediment partitioning throughout much of Earth history.