Showing papers in "Journal of The South African Institute of Mining and Metallurgy in 1979"

The use of activated carbon for the recovery of gold and silver from gold-plant solutions

Abstract: When activated carbon is used for the recovery of gold and silver from Witwatersrand gold-plant solutions, severe fouling of the carbon by calcium carbonate is experienced. Also, difficulty is encountered in the retention of the adsorbed silver on the carbon because it is displaced by gold. The acidification of plant pregnant solutions before they are contacted with carbon was therefore investigated as a means of overcoming these shortcomings. The results from batch laboratory experiments on the effect of pH on gold adsorption from plant solutions and from synthetic solutions of high ionic strength indicated reaction rate optima in the region of pH 5 and below pH I. The effect of pH on the equilibrium capacity constant for gold adsorption onto activated carbon was also studied, using both a plant solution and a synthetic solution of high ionic strength. In the case of the plant solution, the results suggested only a marginal change in carbon capacity for gold in the pH range 12 to 6, with significant increases in capacity at lower pH values. In the case ofthe synthetic solution of high ionic strength, the capacity constant was found to increase steadily as the pH was lowered from 12 to I. It was also found that the gold adsorption capacity of the carbon was significantly better for the synthetic solution. No precipitation of gold from the pregnant solution (gold content approximately 6 gft) was noted as the pH was decreased to values as Iow as ,. However, about 25 per cent of the 0,6 gft silver content was found to have precipitated when a pH value of 3,0 was attained. Further substantial precipitation of silver took place as the pH was lowered further. The investigation was extended by the passing of suitably acidified gold-plant solutions through one or more columns containing activated carbon. Preliminary results showed that the particle size of the carbon had a significant effect on the rate of gold adsorption. No displacement of adsorbed silver by gold was observed to take place at an influent pH of 5. In a typical continuous 'merry-go-round' operation involving three columns in which gold was eluted from the lead column every 48 hours, effluent values averaging 0,001 gft gold could be consistently achieved under simulated plant-operating conditions. The results were obtained at relatively high velocities of influent solution, resulting in very little hold-up of gold in the carbon-recovery circuit. More than 99,9 per cent of the gold and more than 99,8 per cent of the silver was recovered in the adsorption circuit, while the elution data indicated an average elution recovery of 99,8 per cent of the adsorbed gold and 98,2 per cent of the adsorbed silver. Elution of the carbon was carried out at 91 QC.This involved pretreatment of the carbon with a sodium cyanide solution, followed by elution with deionized water. At a loading flowrate of 66 bed volumes per hour, the indicated take-up of metals on the carbon in the lead column was as follows; 53 kgft gold, 6 kgft silver, 57 kgft copper, 14 kgft nickel, and I kgft zinc. Only a trace of cobalt was adsorbed. At an elution rate of 1,7 bed volumes per hour, the lead column was found to be completely stripped in under 5 hours, with concentrations of gold in the eluate reaching 6 to 7 gfl. Besides the excellent adsorption and elution results obtained when acidified pregnant solution was used, no fouling of the carbon was indicated, and the pressure drop across the three columns was considered to be well within practical limits. When compared with conventional zinc precipitation, the carbon process would appear to have considerable economic merit, with strong indications that significant savings would be possible both in capital and operating costs. Further pilot-plant experiments, preferably on a gold plant, would be required before a meaningful cost comparison could be made with the existing process.

Computer simulation of mining in faulted ground.

Abstract: This paper descriptionbes a numerical procedure for the computation of the displacements and stresses induced by the mining of a tabular ore deposit in faulted ground. The numerical procedure is based on the displacement discontinuity method, which can be regarded as an application of Salamon's 'face element principle' to cases in which the reef plane is faulted into several sections, or even folded in an arbitrary way. An element of a fault is modelled in the same manner as an element of the reef, except that a fault element is allowed to undergo permanent inelastic deformation (i.e., slip) if the stresses transmitted through the fault-filling material satisfy a Mohr-Coulomb yield condition. An iterative technique for the incorporation of a Mohr-Coulomb yield condition in the general displacement discontinuity method is explained. This technique is illustrated by means of a simple example involving the mining of a flat-lying reef intersected by a fault. The displacements and stresses at selected locations along the fault are examined as the reef is mined, element by element. A consideration of the energy changes reveals that the occurrence of slip along a fault leads to a sudden increase in the energy release rate due to mining as the excavation intersects the fault. The energy release rate then falls off abruptly to a value less than that which would occur in the absence of any slip, and gradually builds up to re-establish the conditions that would exist in unfaulted ground.

Developments in the application of carbon-in-pulp to the recovery of gold from South African ores

Abstract: An account is given of developments in the use of activated carbon for the recovery of gold from cyanide solutions. ~ carbon-in~pulp process employed at the Homestake Mine is descriptionbed, and its various applications in South Africa and their effectiveness are discussed. Probable future work on the carbon-in-pulp process and other possible applications of carbon for the recovery of gold are outlined.

The kinetics and mechanism of the non-oxidative dissolution of some iron sulphides in aqueous acidic solutions

Abstract: The kinetics ofthe non-oxidative dissolution in acids of the iron sulphides FeS, Fe-FeS, and Fe.S1o were studied by the use of rotating-disc electrodes of the various compounds. It was found that the rates of dissolution vary by orders of magnitude with changes in surface potential. The dissolution rates depend on non-integral orders of hydrogen-ion concentration, which in turn vary with potential. A mechanism based on the following premises is proposed to explain the kinetics of dissolution of the iron sulphides. (I) Only an FeS compound that is exactly stoichiometric dissolves in accordance with the accepted theory of ionic charge transfer. (2) Any non-stoichiometric iron-deficient iron sulphides must be reduced to exactly stoichiometric FeS before spontaneous non-oxidative dissolution can occur. The dissolution of Fe.S1o and slightly iron-deficient FeS compounds under open-circuit conditions occurs only when an oxidation reaction (usually the oxidation of hydrogen sulphide to elemental sulphur) can provide the electrons necessary for the production of exactly stoichiometric FeS. The establishment of such a mixed-potential system is the reason for the induction period that occurs during the dissolution of pyrrhotites in acids.

A modern study of the kinetics and mechanism of the cementation of gold

Abstract: A detailed fundamental study has been made of the various factors that influence the partial reactions comprising the electrochemical model of the cementation of gold from cyanide solutions by zinc. The effects of cyanide concentration, pH, agitation, additions of lead, and the presence of various impurity ions on both the anodic dissolution of zinc and the cathodic reduction of gold have been investigated. The results are used to explain the influence of these variables on the rate of cementation, and possible implications of this work for plant practice are discussed.

Reactions in the production of high-carbon ferromanganese from Mamatwan ore

Abstract: The influence of Iscor coke and Delmas coal on the reduction of Mamatwan manganese ore to ferromanganese was examined by use of a variation of the 'stationary charge in controlled environment' (SCICE) technique. The charges of Mamatwan ore and the appropriate reducing agent were heated to temperatures between 1300 and I600 i?½C and either allowed to cool immediately the required temperature had been reached or held at that particular temperature for periods of up to ... hours. The heating rate was 350i?½C per hour, the particle size of the ore was between 2,83 and 12,7 mm, and the particle size of the reducing agent was between 2,83 and 6,35 mm. After being allowed to cool in air, the reacted charges were examined by optical microscopy, X-ray-diffraction analysis, scanning electron microscopy, and electron-microprobe analysis. No significant difference was found between the changes observed during the reduction of Mamatwan manganese ore by Iscor coke and by Delmas coal. A hypothesis is advanced to explain the mechanism of formation of the Fe-Mn-C alloy.

Iron-smelting furnaces and metallurgical traditions of the South African Iron Age

Abstract: A short survey is given of the Iron Age smelting sites and smelting furnaces that have been found in South Africa. An ""ttempt is made to classify South African smelting furnaces by the inclusion of functional characteristics such as the numbers and positions of tuyeres. An affinity is suggested between the Venda (eastern Transvaal) type of furnace and an East African type. The principles of the smelting process in South African Iron Age furnaces and the characteristics of the smelting products are discussed. Results of metallographic and chemical analyses of 19 iron specimens found at South African sites are given and compared with those from sites in Zimbabwe-Rhodesia, Mocambique, and Nigeria. The carburization and steeling of iron during primitive smelting and forging are discussed.

Wet high-intensity magnetic separation for the concentration of Witwatersrand gold-uranium ores and residues

Abstract: Wet high-intensity magnetic separation (WHIMS) for the concentration of gold and uranium was tested on many Witwatersrand cyanidation residues, and on some ores and flotation tailings. The results varied, but many indicated recoveries of over 60 per cent of the gold and uranium. The main source of loss is the inefficiency of WHIMS for material of smaller particle size than 20fLm. The recoveries in the continuous tests were lower than those in the batch tests. The continuous tests indicated an operational difficulty that could be experienced in practice, namely the tendency for wood chips and ferromagnetic particles to block the matrix of the separator. It was decided that a solution to the problem lies in the modification of the separator to allow continuous removal of the matrix for cleaning. A system has been developed for this purpose and is being demonstrated on a pilot-plant scale. Promising results were obtained in tests on a process that combines a coarse grind, gravity concentration, and WHIMS. In the gravity-concentration step, considerable recoveries, generally over SOper cent, of high-grade pyrite. were obtained, together with high recoveries of gold and moderate, but possibly important, recoveries of uranium. A simple model descriptionbing the operation ofthe WHIMS machine in terms ofthe operating parameters is descriptionbed. This should reduce the amount of empirical testwork required for the optimization of operating conditions and should provide a basis for scale-up calculations. The economics of the WHIMS process is discussed.

The effect of body motion on convective heat transfer from a nude man

Abstract: The effect of body movement on convective heat transfer from a man performing a block-stepping task was investigated experimentally by direct measurements of convective heat transfer. A series of experiments was conducted in which a nude man was required to stand at rest or to block step at 12 and 24 steps per minute. Wind speed, which was kept constant during each experiment, spanned the range 0,5 to 3,5 m/so Air temperature was kept constant at 43 i?½C in all the experiments. The results showed conclusively that the convective heat-transfer coefficient depends on the stepping rate. The effect of body motion can be regarded as being equivalent to an increase in the velocity of the free stream. The equivalent increase in air speed was found to be 0,36 and 0,77 m/s for 12 and 24 steps per minute respectively. Data from various sources, including the present study, indicate that wind speed should be increased by about 0,30,0,55, and 0,80 m/s to account for Iow, moderate, and vigorous body movements respectively. These findings are of direct relevance to the practical assessment of heat stress.

An integrated mining and extraction system for use on Witwatersrand mines

Abstract: An account is given of the development of a process to concentrate gold and other valuable minerals and to produce a discardable waste. In this process, the ore is coarsely milled, a bulk flotation concentrate is prepared, and the flotation tailing is scavenged in a hydrocyclone, which returns coarse gangue, moderately coarse valuable minerals, and locked valuable minerals back to the mill. The engineering developments required by this circuit in order that it will fit underground, and the progress made towards the achievement of those requirements, are reviewed. Ifthe waste is to be suitable for use as a backfill in a deep-level, flat tabular excavation, it should be capable of being placed hydraulically, and should have both Iow voidage and high rates of drainage. Such a material could be prepared by the fine screening of the overflow from the cyclone in the proposed circuit. Possible methods for the handling of the concentrate and the recovery of its valuable constituents are descriptionbed. The paper concludes with a discussion of the possible benefits from the use, in deep-level Witwatersrand mines, of a system involving concentration underground, extensive backfilling using the tailings from the concentration process, and hydraulic hoisting of the concentrate. SAMEVATTING Daar word verslag gedoen oor die ontwikkeling

Pressure leaching of uranium-bearing Witwatersrand ores

Abstract: Since 1955 extensive pressure-leaching testwork has been conducted by Anglo American Research Laboratories (AARL) in laboratory-scale batch autoclaves. In 1958 a small continuous pilot-plant of 45 kg of solids per hour was operated by AARL. In 1974, when high uranium prices were anticipated, Anglo American, encouraged by successful commercial-scale autoclave operations as practised by Outokumpu, Sherritt Gordon, and Impala Platinum, decided to install a continuous pilot plant at Western Deep Levels. At that time the proposed pilot plant was considered to be of prototype size. The project was funded by members of the Nuclear Fuels Corporation (Nufcor). Since its commissioning in February 1977, the pilot plant at Western Deep Levels, which can treat between 10 and 20 tons of dry solids per hour, has been used to test ores from four different mines. The paper compares the uranium extractions and pyrite oxidation obtained in laboratory batch autoclaves with those obtained in the continuous pilot plant. In general, differences in uranium extraction are not great and can be explained; the differences in pyrite oxidation are less well understood. The effect on plant design of the evolution of carbon dioxide during leaching is discussed. Evaluation of the equipment and materials of construction would have been almost impossible in a small-scale batch autoclave. It is doubtful whether such results would have generated the necessary confidence to permit decisions to install a commercial-size plant. The development and performance of the multistage pumps, instrumentation, shaft seals, and shaft-seal water treatment are discussed. It is concluded that the operation of a large-scale continuous pressure-leaching pilot plant to supplement laboratory batch autoclave tests has been a necessary part of the development of this process.

The roasting and leaching of Witwatersrand pyrite concentrates

Abstract: Many of the pyrite concentrates produced at South African gold and uranium mines contain economically significant amounts of nickel, copper, and cobalt, apart from gold and uranium. In some cases these concentrates are leached for uranium, followed by roasting and cyanidation of the calcine for the extraction of the gold. Even if their intrinsic value is excluded, the presence of appreciable amounts of base metals can lead to excessive consumption of cyanide and zinc in the conventional process for the recovery of gold from calcines. The extent to which base metals, particularly cyanocides in the calcine, can be made soluble in water or in dilute acid by variation of the pyrite roasting conditions was investigated. An important finding of the investigation was that the conditions producing favourable base-metal sulphation (and hence solubility in water) also produced good sulphation of the uranium values that had not been extracted in a conventional leach of the original pyrite. Thus, if the pyrite is subjected to a sulphating roast followed by quenching in water (or dilute acid), it should be possible for the uranium to be extracted in improved yield. The need for leaching of the pyrite would therefore fall away. It was noted that sulphation roasting also resulted in improved gold extractions when the calcine was subsequently subjected to conventional cyanide-extraction procedures. From well-sulphated calcine, the dissolution of base metals and uranium appeared to be fairly independent of leaching pH, time, and temperature. On an inadequately sulphated calcine, Iow pH values during leaching gave increased extraction of copper and uranium but did not have a significant effect on the dissolution of nickel and cobalt. The extraction of uranium increased with increasing leaching time and temperature, while only longer times at a Iow pH value markedly improved the extraction of copper. The extraction of cobalt was fairly independent of leaching time and temperature, but the results were insufficient for a conclusive evaluation to be made of their effects on the dissolution of nickel. A cursory economic assessment 'indicated that sulphation roasting applied to the pyrites investigated is likely to be very profitable.

Slag-metal equilibrium in the production of low-carbon ferromanganese

Abstract: An investigation was conducted into the reactions between the slag system MnO-CaO-MgO-SiO.-(AI.O3) and the alloy system Mn-Fe-Si-(C). Synthetic slags representative of plant melts and a plant alloy were reacted in alumina crucibles at temperatures of 1400i?½C, 14S0i?½C, ISOOi?½C, and 1600i?½C. In similar experiments, slags were used that comprised a South African manganese ore with various amounts of lime and several synthetic alloys with various silicon contents and manganese-to-iron ratios. These experiments were conducted in a vertical molybdenum-wound resistance furnace with full temperature control. Slag-to-alloy ratios were also varied during the tests. The rate of reduction of Mn.O3 and the MnO from the slag by the silicon in the alloy was extremely rapid, most of the reaction being completed within five minutes. The strongly exothermic nature of the reaction resulted in considerable generation of heat at the slag-alloy interface, causing convectional stirring ofthe contents of the crucible and promoting the rate of reaction. Equilibrium was usually attained after fifteen minutes. The major limitation governing the recovery of manganese is the need for the silicon content of the alloy to meet a maximum specification of 2 per cent. Higher concentrations of silicon in the final alloy of between 8 and 12 per cent favour good recoveries of manganese from the slag, but, since such an alloy is not salable, lower recoveries must apparently be tolerated. In alloys of 2 per cent silicon, Iow activities of the silicon are responsible for poor recoveries of manganese. The activity of MnO in the slag can be increased by moderate additions of CaO and small amounts of MgO, i.e., by an increase in the basicity of the slag.

The hydraulic cleaning of stopes

Abstract: Union Corporation are experimenting with a high-pressure water jet to remove blasted rock from short panels. The advantages are that the jet provides a highly efficient, flexible, and mobile cleaning tool that eliminates much of the lashing. Cost estimates show it to compare favourably with the existing system, with potential savings of 30 cents per ton milled. Equipment and method trials are continuing with the ultimate objective of eliminating hand lashing entirely while retaining the flexibility of the present method of mining.

Hopper clarification of gold pregnant solution at Vaal Reefs South

Abstract: High-rate floc-blanket clarification of gold pregnant rotary filtrate was introduced at the Vaal Reefs South gold plant ofthe Anglo American Corporation during February 1978. A. daily 12000 to 15 O~Ot of filtrate, with an average suspended-solids concentration of 350 mg/I, is continuously clarified to a concentration of less than 2S mg/I of suspended solids in a modified plant pachuca (10 m in diameter) at throughput rates of 7,7 to 8,5 ma/m2.h by the addition of 5 g/t of ferric chloride inorganic coagulant and 0,2 g/t of Superfloc NI 00 flocculant. The pachuca overflow is then clarified further in seven Stellar candle pressure filters of 54,S m2 surface area to under 5 mg/I of suspended solids. The combined clarification cost when the hopper clarifier is used in conjunction with the Stellar filters is RO,O032 per ton of liquid treated, which is approximately 60 per cent lower than the cost of Stellar filtration on its own. The savings are mainly due to the reduced use of filter pre-coat, the consumption of which has dropped by 70 per cent since the introduction of hopper clarification.

Stope-face conveyors for gold mines

Abstract: The results of trials with three stope-face cleaning systems are descriptionbed. Two of these systems were based on armoured chain conveyors, and the third on a reciprocating-flight conveyor. The operational elements of each system are discussed with reference to their effectiveness, and many problems are highlighted. It is concluded that the reciprocating-flight conveyor is superior, and has the potential for being developed into a system yielding a labour productivity of more than 30 m2 per worker per month and a face advance of 15 m per month working one shift a day.