Showing papers in "The Journal of Physical Chemistry in 1952"

Molecular compounds and their spectra. 3. the interaction of electron donors and acceptors

Abstract: : Electron donors (D) and acceptors (A) are classified into types based on their structure before interaction. Interactions were either dissociate (chemical displacement reaction) or associative (molecular-complex or -compound formation). Pair types included molecular complexes (D-A), molecular compounds (D yields A), and bimolecular displacement reactions (A+D yields B+C). Probable charge-transfer spectra are tabulated for several molecular complexes.