52 Chemical Shifts and Coupling Constants for C2H4D3O2P

With the aim of learning about the synergistic effect of a combination of (HOCH2)3P and Na2S2O4 for the bleaching of mechanical pulps, reactions of (HOCH2)3P (and its associated precursor, (HOCH2)4P+Cl−) with Na2S2O4 were studied in aqueous media under Ar and in air. The secondary phosphine (HOCH2)2PH is the major product in a 1:1 reaction of (HOCH2)3P and Na2S2O4 under Ar, the formaldehyde being removed in the form of HOCH2SO3Na and HOCH2SO2Na; the latter is Rongalite, itself an industrial bleaching agent. Significant amounts of the primary phosphine HOCH2PH2 are also seen. When the reaction is performed in air, the oxide (HOCH2)2P(O)H is the main product. Reaction of (HOCH2)4P+Cl− with Na2S2O4 (even under Ar) leads to solely the oxidation products: (HOCH2)3PO, (HOCH2)3PS, and (HOCH2)2P(O)OH. 31P{1H} and 1H NMR spectral data for secondary and primary (hydroxymethyl)phosphines and their oxidation products are reported for the first time. The toxicity of the primary and secondary phosphines is lik...

52 Chemical Shifts and Coupling Constants for C2H4D3O2P

References

Characterization of Secondary and Primary (Hydroxymethyl)Phosphines and Their Oxidation Products: Synergism in Pulp-Bleaching

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