Journal ArticleDOI
Anomalies in the “latent heat” of solidification of supercooled water
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In this paper, the latent heat for the solid-liquid transition, measured in supercooled water down to −30°C, is reported for the first time, and the authors suggest the existence of a metastable phase (or phases) in freshly formed ice, relaxing to the equilibrium lh configuration.About:
This article is published in Chemical Physics Letters.The article was published on 1985-09-20. It has received 32 citations till now. The article focuses on the topics: Latent heat & Phase (matter).read more
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Thermodynamics of supercooled water.
TL;DR: In this article, the existence of a liquid-liquid critical point in supercooled water was considered and the theory of critical phenomena can give an accurate account of the experimental thermodynamic-property data up to a pressure of 150 MPa.
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Thermodynamics of supercooled water
TL;DR: It is concluded that critical-point thermodynamics describes the available thermodynamic data for supercooled water within experimental accuracy, thus establishing a benchmark for further developments in this area.
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Volume of supercooled water under pressure and the liquid-liquid critical point.
TL;DR: The volume of water (H(2)O) was obtained by using emulsified water and the plot of volume against temperature showed slightly concave-downward curvature at pressures higher than ≈200 MPa, compatible with the liquid-liquid critical-point hypothesis, but hardly with the singularity-free scenario.
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Heat capacity anomaly in a large sample of supercooled water
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Equation of State for Supercooled Water at Pressures up to 400 MPa
TL;DR: In this paper, an equation of state for the thermodynamic properties of cold and supercooled water is presented for temperatures from the homogeneous ice nucleation temperature up to 300 K and for pressures up to 400 MPa.
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Heat capacity of water at extremes of supercooling and superheating
TL;DR: In this article, low temperature heat capacities for water and deuterium oxide have been remeasured using different sample preparation and data analysis procedures from those used in the original studies of this anomalous region.