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Coating containing acrylosilane polymer to improve mar and acid etch resistance

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TLDR
In this paper, the authors proposed a coating composition particularly useful as a clear coating used over a pigmented base coat that has improved cure, which provides increased out of oven hardness, as well as improved mar and scratch resistance, and increased environmental chemical resistance.
Abstract
The present invention relates to a coating composition particularly useful as a clear coating used over a pigmented base coat that has improved cure, which provides increased out of oven hardness, as well as improved mar and scratch resistance, and increased environmental chemical resistance. The composition is comprised of 40 - 70% by weight of film forming binder and 30 - 60% by weight of a volatile liquid carrier for the binder; wherein the binder contains a 25 - 98.5% by weight, based on the weight of the binder, of a silane polymer, 1 - 40% by weight, based on the weight of the binder, of an alkylated melamine crosslinking agent, 0.5 - 5% by weight, based upon the weight of the binder, of an aryl or alkyl acid phosphate curing agent, and 0 - 30% by weight, based upon the weight of the binder, of a non aqueous dispersed polymer, a urethane polymer, a polyester resin, an acrylic polyol resin, or any mixture thereof. The composition may be used, in particular, as a finish for automobiles and light trucks.

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References
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Coating containing acrylosilane polymer to improve mar and acid etch resistance

TL;DR: In this paper, a clear acrylic polymer is used to improve resistance to marring and acid etching when exposed to natural weathering conditions, and the acrylic polymer has a volatile liquid carrier for the binder.
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Thermosetting silicon-containing composition

TL;DR: In this article, a thermosetting composition comprising a resin having hydroxyl group, a silyl group-containing polymer, a hydrolyzable silicon compound and a curing catalyst is used.
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Coating containing hydroxy containing acrylosilane polymer to improve mar and acid etch resistance

TL;DR: A coating composition particularly useful as a clear coating used over a pigmented base coat that has improved resistance to marring and to acid etching when exposed to natural weathering conditions is presented in this article.
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Coatings that may comprrise reactive silicon oligomers

TL;DR: In this article, a graft copolymer having an acrylic polymer based backbone and stabilizing arms comprising ethylenically unsaturated monomer, the backbone being insoluble and the arms being soluble in the composition is defined.