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Composite electroplated steel sheet and its production

TLDR
In this article, a composite plated steel sheet having excellent resistance to corrosion was produced by using composite plating liquid prepd. by adsorbing a specific amt. of Na 2+, etc.
Abstract
PURPOSE: To produce a composite plated steel sheet having excellent resistance to corrosion by using a composite plating liquid prepd. by adsorbing a specific amt. of Na 2+ , etc. on oxide particles of SiO 2 , etc. having a specific grain size, charging electrostatically positive the particles and dispersing the same in a specifically composed zinc alloy plating bath in plating the steel sheet. CONSTITUTION: A material prepd. by adsorbing one or ≥2 kinds among Ni 2+ , Fe 2+ and Co 2+ at ≥2mg for each 1g on a mixture composed of one or ≥2 kinds among SiO 2 , TiO 2 , ZrO 2 , Nb 2 O 5 , Ta 2 O 5 , Al 2 O 3 having 1W100μm grain size and charging electrostatically positive the mixture is dispersed at 10W150g/l into a zinc alloy plating bath contg. 10W100g/l Zn 2+ and 5W70g/l in total of one or ≥2 kinds among Ni 2+ , Fe 2+ and Co 2+ and the pH thereof is adjusted to 1W4, by which a composite plating bath is prepd. A steel sheet is electroplated by using such composite plating bath, by which the composite electroplated steel sheet having the much improved corrosion resistance is obtd. COPYRIGHT: (C)1985,JPO&Japio

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Patent

Zinc-plated metallic material

TL;DR: A zinc-plated metallic material resistant to corrosion at elevated temperatures comprising a metallic material; a plating layer consisting of zinc or zinc alloy containing 70% by weight or more of zinc; and a coating layer on the plating, comprising 10 to 5,000 mg. of magnesium oxide or hydrated magnesium oxide and 50 to 5k mg of chromium oxide per square meter of the coating layer.
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