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Curing composition, production of the same and cured material

TLDR
In this article, a subject composition containing a hydrolysate of an alkylsilicate and a specific solvent, capable of being used singly as a hard coat and obtaining a coated membrane excellent in heat resistance, weather ability, antifoulancy, chemical resistance, etc., by blending with a resin, etc.
Abstract
PROBLEM TO BE SOLVED: To obtain the subject composition containing a hydrolysate of an alkylsilicate and a specific solvent, capable of being used singly as a hard coat and obtaining a coated membrane excellent in heat resistance, weather ability, antifoulancy, chemical resistance, etc., by blending with a resin, etc., and useful for a coating material, an adhesive, etc. SOLUTION: This curing composition contains (A) a hydrolysate of a alkylsilicate (A 1 ) (e.g. a fine particle like material containing methoxy or ethoxy group and having <50Å inertial radius) and (B) a solvent having a higher boiling point than that of alcohol generated by the hydrolysis of (A 1 ) (e.g. a solvent not having a group capable of making an ester interchange with alcohol of the component (A) such as methyl isobutyl ketone and xylene, propylene glycol monomethyl ether and diethylene glycol monoethyl ether). COPYRIGHT: (C)1997,JPO

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Radiation-curable resin composition and cured product thereof

TL;DR: A radiation-curable resin composition comprising an inorganic component containing a silica particle composed of a hydrolyzate of an oligomer of an alkoxysilane and a monomer and/or an oligomers thereof, wherein viscosity at 25° C. is from 1,000 to 10,000 centipoises as mentioned in this paper.
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Radiation hardenable resin composition and its hardened product

TL;DR: In this paper, the authors proposed a radiation hardenable resin composition, which, while having transparency, high adhesiveness and adhesive characteristics with an elapse of time, possesses sufficient strength and low hardening shrinkage even when formed into a thick coat.
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Silicate polymer and its production method, and coating agent containing the silicate polymer

TL;DR: In this paper, the authors proposed a method to obtain a silicate polymer of a high molecular weight and excellent in storage stability in the solution state, and a film obtainable from this silicates polymer suitably used as an insulating film for a semiconductor device or a gas barrier film.
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Method for synthesis of pre-hydrolyzed alkyl polysilicate

TL;DR: In this paper, a two-step synthesis method of a pre-hydrolyzed alkyl polysilicate is proposed, where a silica precursor hydrated to 90 to 100% is added to maximize a condensation reaction rate, and another pre-silica precursor is added at 25 to 70% to terminate the reaction.
References
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Patent

Curable composition and process for producing the same

TL;DR: In this article, a curable mixture consisting of an aged mixture of tetramethoxysilane with water added in excess of the theoretical amount sufficient for the hydrolysis and condensation of 100% of the silane was presented.
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Curable composition and its preparation

TL;DR: In this article, a silicone-modified acrylic copolymer is used to create a coating on a variety of base materials by blending a specific organosilicon compd with water in an amt at least necessary for hydroysis and condensation thereof.
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Transfer foil, protective layer for transfer foil, and manufacture of composition for forming of protective layer for transfer foil

TL;DR: In this article, the authors proposed a method to improve scratch resistance and weather resistance by a method wherein a releasant layer is provided on one side surface of a base material, and a transfer film composed of a protective layer, a metalized layer, and an adhesive layer is formed.
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Coating fluid and its production

TL;DR: In this article, the subject fluid comprises an acrylic polyol prepared by copolymerizing (i) 1-80wt.% monomer containing hydroxyl group (e.g. 2- hydroxyethylacrylate), and (ii) a hydrolyzed condensate formed by adding water in an amount of more than that of theoretically 100% capable of performing the hydrolyzing condensation.