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Electroplating pretreatment method for acrylonitrile butadiene styrene (ABS) plastic surface

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TLDR
In this article, an electroplating pretreatment method for an acrylonitrile butadiene styrene (ABS) plastic surface was proposed, in which metal palladium activation is not used.
Abstract
The invention relates to an electroplating pretreatment method for an acrylonitrile butadiene styrene (ABS) plastic surface The electroplating pretreatment method comprises the following process steps of: eliminating stress, performing alkali washing for oil removal, pickling, roughening, performing neutralizing treatment, performing chemical activation, and performing the conventional electroplating, wherein in the chemical activation process, plastic base materials are put in to an activation solution and are subjected to hyperthermic treatment in a water bath for a certain period of time, each liter of the activation solution comprises 10 to 12g of nickel sulfate, 20 to 25g of sodium hypophosphite and 5 to 8g of sodium citrate, the pH is 9 to 11, and the temperature is between 70 and 75 DEG C In the invention, a novel method in which metal palladium activation is not used is provided, can be used for replacing a sodium borohydride and methanol activation process and contributes to environment friendliness; and on the basis of pretreatment, the plastic surface can be directly electroplated, so that the problems of complicated treating processes, high PdCl2 prices, high pollution possibility of a plating solution and the like are solved

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Plastic surface treatment method

Shen Yuzhong
TL;DR: The plastic surface treatment method is simple in process; the treated plastic is easy to glue and high in joint strength as discussed by the authors, but it is not suitable for use in medical applications.
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Transparent acrylonitrile butadiene styrene (ABS) hydroelectric plating production process method

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References
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Process for metallization of plastic surfaces

TL;DR: In this article, a process for chrome-free metallization of plastic surfaces by which a plating film adhering tightly to the surface of a plastics part can be formed and which is free from the deposition on a jig is described.
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TL;DR: In this paper, a no-palladium activating solution recipe for chemical nickel plating on plastic surface and its technological process is presented. But the activation process is not described.
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TL;DR: In this article, a method for the palladium activation-free phosphorous-nickel alloy chemical plating of the surface of TiB2 powder, which is characterized by comprising: a step of pretreatment, in which the TiB 2 powder is subjected to heat treatment by a process of 300 to 500 DEG C constant temperature treatment.