Journal ArticleDOI
Energy transfer from O(1D) to O2
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In this paper, the authors show how fluid dynamical effects can produce a 50-fold reduction in downstream O 2 (1Σ + g) when O( 1 D) is quenched by O 2 and favour a near unit probability.About:
This article is published in Chemical Physics Letters.The article was published on 1970-05-01. It has received 12 citations till now.read more
Citations
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Journal ArticleDOI
Optical Emission from O(1D) and O2(b 1Σg) in Ultraviolet Photolysis of O2 and CO2
TL;DR: The presence of O(1D) has been detected via 6300 A emission in ultraviolet photolysis of O2 and CO2 Quenching rates for O( 1D) and O2(1Σg) have been measured for O2, N2, CO2, and CO as mentioned in this paper.
Journal ArticleDOI
Rate constants for the gaseous interaction of O(21D2) and O(21S0 - a critical evaluation
TL;DR: In this article, an extensive critical evaluation has been completed of all the available rate coefficients and their temperature dependences that describe the interactions of gaseous O(21D2) and O(S0) with numerous species.
Book ChapterDOI
Aeronomic Reactions of Hydrogen and Ozone
TL;DR: Bates and Nicolet as mentioned in this paper showed that the aeronomic behavior of ozone was related to the dissociation of molecular oxygen below 100 km and therefore, therefore, that ozone was important above 100 km.
Journal ArticleDOI
Mechanism of Singlet Molecular Oxygen Formation from Photolysis of Ozone at 2537 Å
M. Gauthier,D. R. Snelling +1 more
TL;DR: In this article, photolysis and the reaction of O(3P) and O(1D) with O3 are discussed as sources of both O2 singlet states, and the relative rates of removal by O2, N2, and O3 were found to be 1:0.7:9.
Journal ArticleDOI
Relative Rate Constants for Reactions of O(1D) Atoms Generated by Flash Photolysis of Ozone
P. M. Scott,R. J. Cvetanović +1 more
TL;DR: In this article, the relative rates of O(1D) reactions with H2O vapor and O2 have also been determined and the values obtained are compared with the data in the literature.
References
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Journal ArticleDOI
Deactivation of O(1D)
Robert A. Young,Graham Black +1 more
TL;DR: In this article, the authors measured the emission rate of O2(b 1 εg+) produced in the energy transfer reaction O(1D)+O2→O2b 1εg+O(3P), whose rate coefficient is greater than 10−11 cm3/sec, as a function of [O2] and [He].
Journal ArticleDOI
Deactivation of O(1S) and O2(b1Σg
F. Stuhl,K. H. Welge +1 more
TL;DR: In this article, the rate constants for collisional deactivation of O(1S) and O2(b1Σg+) were obtained by measuring the intensity decay of the O( 1S)→ 1D and O 2(b 1 Σg+
Journal ArticleDOI
The collisional deactivation of O2(1Δg)
Ian D. Clark,Richard P. Wayne +1 more
TL;DR: O2(1Δg) is quenched at a room temperature rate constant of 2.2 ± 0.1 by O2 and roughly 4 × 10−19 cm3 molec−1 sec−1 by dry air.
Journal ArticleDOI
Energy transfer from O(1D) to O2
T.P.J. Izod,Richard P. Wayne +1 more
TL;DR: In this article, the energy transfer process O( 1 D) + O 2 ( 3 Σ − g ) → O 2( 1 Σ + g ) + O( 3 P) has been assessed relative to the efficiency of quenching.