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New diamino compound and photoreceptor using the same

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TLDR
In this article, the Ullmann reaction was used to obtain a new diamine compound, useful as a charge transport layer of photoreceptors or electroluminescent elements.
Abstract
PURPOSE:To obtain a new diamine compound, useful as a charge transport layer of photoreceptors or electroluminescent elements, capable of providing the photoreceptors excellent in characteristics such as sensitivity, charge transport properties or initial surface potential and improved in ozone resistance and light stability CONSTITUTION:A diamine compound expressed by formula I (Ar1 and Ar2 are alkyl, aralkyl, etc; R1 to R4 are H, alkyl, etc; X is O, S, etc), eg a compound expressed by formula II The aforementioned compound is obtained by carrying out the Ullmann reaction of, eg an iodide expressed by formula III with an amino compound expressed by formula IV in the presence of a basic compound catalyst such as a carbonate of an alkali metal in an aprotic polar solvent such as nitrobenzene at 100-250 degC under ordinary pressure For example, N-biphenyl-N-p-tolylamine is used as the amino compound expressed by formula IV

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