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Polymeric dye having xanthene skeleton and water-base ink composition containing this dye

TLDR
In this paper, the authors presented a method to obtain the dye which shows a magenta color of high color tone when dissolved in water and improved in solubility, storage stability and light resistance by chloro-sulfonating a xanthene dye and bonding the product of chlorosulfonation with polyallylamine.
Abstract
PURPOSE:To obtain the dye which shows a magenta color of high color tone when dissolved in water and is improved in solubility, storage stability and light resistance by chloro-sulfonating a xanthene dye and bonding the product of chloro-sulfonation with polyallylamine. CONSTITUTION:Acid Red of formula I is reacted with thionyl chloride in dimethylformamide to obtain a brown product of formula II. This product is reacted with a polyallylamine of formula III to obtain a polymeric dye comprising xanthene structural units of formula IV [wherein x is -(CH3)p- or -(CH3)p- CO-; R to R are each H or (un)substituted 1-4C alkyl; X and X are each sulfo or sulfonate; Y is carboxyl or carboxylate; k is 0-2; l+m=0-2; n is 20-300; and p is 0-5, provided that k and l are numbers which must not be 0 simultaneously].

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