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Process for the manufacture of a composite material with refractory fibrous reinforcement and ceramic matrix

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TLDR
A thin, refractory, intermediate adhesive layer of laminar structure is deposited in oriented fashion on the reinforcing fibers by chemical vapor deposition, this intermediate layer having a greater elongation at break than the matrix and having a thickness of between 0.2 and 3 micrometers.
Abstract
A thin, refractory, intermediate adhesive layer of laminar structure is deposited in oriented fashion on the reinforcing fibers by chemical vapor deposition, this intermediate layer having a greater elongation at break than the matrix and having a thickness of between 0.2 and 3 micrometers; the material forming the intermediate layer can be laminar pyrocarbon or boron nitride; the ceramic matrix is then infiltered, preferably by chemical vapor deposition, inside the pores of the reinforcement.

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Fiber-containing composite

TL;DR: In this paper, the mixture is formed into a preform which is infiltrated with a molten solution of boron and silicon producing a composite containing borone nitride coated fibrous material.
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Filament-containing composite

TL;DR: In this paper, Boron nitride is coated on filaments of elemental carbon and/or silicon carbide, the coated filaments are contacted with an infiltration-promoting material containing elemental carbon to produce a preform wherein the filament are substantially parallel and each filament is enveloped with infiltrate-promote material.
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Process for making composite containing fibrous material

TL;DR: A composite is produced by forming tapes comprised of a mixture of infiltration-promoting material and organic binding material, disposing a layer of boron nitride coated fibrous material between at least two of the tapes forming a layered structure, laminating the layered structure to remove organic binding materials and infiltrating the resulting porous body with a solution of Boron and silicon as discussed by the authors.
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Oxidation resistant ceramic matrix composites

TL;DR: Ceramic matrix composites having a boron containing oxygen-scavenging sealant-forming region coextensive with the internal fibers and interface debonding layer and a ceramic matrix material provide superior resistance to oxidation as discussed by the authors.
References
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Fiber reinforced composite product

TL;DR: In this paper, a fiber reinforced composite product is produced in accordance with a process in which yieldable, high strength carbon or graphite fibrous materials are formed into a substrate that has been optimized for final product application through the accurate control of its shape, cross-sectional configuration, density, fiber volume and internal fiber orientation.
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Composite article and method of making same

TL;DR: In this article, a method of composite article and a composite article specifically adapted for use in high temperature, corrosive and errosive environments comprising a carbon fibrous substrate, including a pyrolytic carbon sheath formed about each fiber of the substrate; a metallic carbide, oxide, or nitride compliant coating over the coated fibers of the substrates; and an impermeable metallic carbides, oxide or nitric outer protective layer formed about the entire periphery of the coated substrate.
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Silicon carbide coated graphite members and process for producing the same

TL;DR: A preferred process for producing coated isotropic graphite members comprises: A. HEAT TREATING the ISOTROPIC GRAPHITE MEMBER to a TEMPERATURE from about 1700*C to 2400*C in a halogen atmosphere comprising chlorine or fluorine to reduce the impurity ash content to the range of the order to 2 to 10 ppm, B. ULTRASONICALLY CLEANING the MACHINED graphite BODY in a LIQUID CLEANing FLuid to REMOVE LOOSE SURFACE PARTICLES, D
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Self protecting carbon bodies and method for making same

TL;DR: In this article, a carbon body is composed of a thermochemically deposited coating which renders the body resistant to oxidation at high temperatures, and the coating is formed of a silicon alloy having a non-columnar grain distribution with substantially equiaxial grains of an average diameter of less than one micron.
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Composite silicon carbide/silicon nitride coatings for carbon-carbon materials

TL;DR: In this article, a multilayer coating system for the protection of carbon-carbon composites is described, which includes an inner layer of SiC (produced by a conversion process in which Si is diffused into the carbon substrate) and an outer layer of CVD (chemically vapor deposited) Si3 N4.