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Process for the production of methanol from synthesis gas

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TLDR
The lanthanum rhodate has a perovskite structure and is a highly active catalyst for the production of methanol from hydrogen and carbon monoxide.
Abstract
Lanthanum rhodate, or metal substituted lanthanum rhodate, having a perovskite structure is a highly active catalyst for the production of methanol from hydrogen and carbon monoxide. The lanthanum rhodate displays excellent stability and excellent selectivity to methanol.

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References
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Journal ArticleDOI

Catalysis by Supported Metal Crystallites from Carbonyl Clusters. II. Catalytic Ethanol Synthesis from CO and H2 under Atmospheric Pressure over Supported Rhodium Crystallites Prepared from Rh Carbonyl Clusters Deposited on TiO2, ZrO2, and La2O3

TL;DR: In this paper, the authors showed that ethanol was catalytically produced in the CO-H2 reaction under atmospheric pressure and at 150-250 °C over rhodium crystallite catalysts prepared from Rh carbonyl cluster compounds highly dispersed on La2O3, TiO2, and ZrO2.
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