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Production of ethanol from acetic acid

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TLDR
Ethanol is produced from acetic acid using an olefin having at least 4 carbon atoms, hydrogenating the ester obtained into ethanol, removing the ethanol, dehydrating the higher alcohol back to the original olelin and recycling the olein to esterify the acetic acids as mentioned in this paper.
Abstract
Ethanol is produced from acetic acid by esterifying the acetic acid with an olefin having at least 4 carbon atoms, hydrogenating the ester obtained into ethanol and a higher alcohol having at least 4 carbon atoms, removing the ethanol, dehydrating the higher alcohol back to the original olefin and recycling the olefin to esterify the acetic acid.

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Process for producing ethanol

TL;DR: In this paper, a process for producing ethanol including a combination of biochemical and synthetic conversions results in high yield ethanol production with concurrent production of high value coproducts, such as corn oil, and high protein animal feed containing the biomass produced in the fermentation.
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Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst

TL;DR: In this paper, a process for the selective production of ethanol by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethanol is disclosed and claimed, and an embodiment of this reaction is presented.
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Ethanol production from acetic acid utilizing a cobalt catalyst

TL;DR: In this paper, a process for the selective production of ethanol by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethanol is disclosed and claimed, and an embodiment of this reaction is presented.
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Tunable catalyst gas phase hydrogenation of carboxylic acids

TL;DR: In this paper, a process for the selective formation of ethanol from acetic acid is described, where a feed stream containing hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate.
References
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Preparation of alcohols

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Method of hydrogenating esters

TL;DR: In this article, the authors proposed a method for the hydrogenation of esters to alcohols in the liquid phase in the presence of highly efficient catalysts containing oxides of copper with or without oxide of other hydrogenating metals.
Patent

Catalyst for ester hydrogenation

TL;DR: In this paper, a process for hydrogenation of esters to alcohols is described, which comprises contacting the ester with hydrogen and a catalyst comprising cobalt, zinc and copper under catalytic hydrogenation conditions including a temperature between 150° and 450° C and a pressure of 500-10,000 psig.