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Protonic Conductivity and Superionic Phase Transitions in Inorganic Sulphates and Selenates

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This article is published in Solid State Phenomena.The article was published on 1994-12-01. It has received 4 citations till now.

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Protonic conductivity at the superionic phase transitions in the M3H(XO4)2 crystal group

TL;DR: In this paper, a microscopic model for the description of the proton subsystem dynamics in superionic crystals with hydrogen bonds is developed, where the effect of the displacement of the nearest oxygens during hydrogen-bond formation is taken into account.
Journal ArticleDOI

The superionic phase transition in hydrogen-bonded systems of the M3H(XO4)2 class: the effect of nearest-O(2) distortions on the proton dynamics

TL;DR: In this article, the behavior of protonic conductivity at the transition between the superionic state with a disordered system of hydrogen bonds and low-temperature states at which the different types of ordering in the H-bond network appear is investigated.
Journal ArticleDOI

Raman studies of superionic phase transition in (NH4)4H2(SeO4)3

Maria Połomska, +1 more
- 01 Sep 1996 - 
TL;DR: In this paper, NIR FT Raman spectroscopy was used to investigate molecular groups dynamics in the vicinity of superionic phase transition in (NH4)4H2(SeO4)3.
Journal ArticleDOI

The roles of “ammonium” and “hydrogen-bond” protons in single crystals of the superionic conductor NH4HSeO4 by 1H NMR relaxation

TL;DR: In this paper, the variations with temperature of the line-shape, spin-lattice relaxation time, T1, and spin-spin relaxation time T2, of the 1H nuclei in NH4HSeO4 single crystals were investigated, and with these 1H NMR results, they were able to distinguish the crystals' "ammonium" and "hydrogen-bond" protons.
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