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Purification of salt containing waste water by wet oxidation at supercritical conditions

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TLDR
In this paper, the supercritical zone is enclosed by a subcritical jacket stream formed from cooling water, and the reaction is carried out in the form of a flame (5).
Abstract
In the process according to the invention for the purification of salt-laden waste water by wet oxidation of organic constituents at supercritical conditions, the reaction is carried out in the form of a flame (5). The supercritical zone is enclosed by a subcritical jacket stream (4) formed from cooling water. At one end of the reactor (1) designed as a cylindrical pressure vessel at least one burner nozzle (2) and at least one annular cooling water feed position (48) surrounding the burner nozzle are provided; at the other end, at least one collective exit position (160) for cooling water, reaction products and, in particular, precipitated salts are arranged. Because of the jacket stream, there are no blockages due to salts; corrosion problems are substantially neutralised.

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TL;DR: In this article, a supercritical oxidation system using a cooled-wall shell is described, where the shell is cooled either by its own feed from the system or by a fluid external to the process, and therefore requires less thickness, the cooling in both cases having a pressure similar to that of the oxidation process.
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Desalting and salt discharging control method for supercritical water oxidation systems

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References
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Method for solids separation in a wet oxidation type process

TL;DR: In this paper, a two-zone pressure vessel is proposed for aqueous phase oxidizer and solids separator, in which precipitates and other solids fall or are sprayed from a supercritical temperature super zone into a lower temperature sub zone.
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Supercritical fluids as diluents in combustion of liquid fuels and waste materials

TL;DR: In this article, supercritical fluids are used as viscosity reduction diluents for liquid fuels or waste materials, which are then spray atomized into a combustion chamber and improved combustion efficiency.
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Method for suspercritical water oxidation

TL;DR: In this article, a subcritical temperature fluid (65) is introduced into the upper region of the reactor vessel (10) so as to establish a downflow of the subcritical fluid through the supercritical temperature zone (20) along the inside surface of the vessel wall (12).