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Removal of nitrogen oxide from exhaust gas

TLDR
In this paper, a process for removing nitrogen oxide from exhaust is disclosed, comprising contacting exhaust containing nitrogen oxide with an alumina catalyst which contains not more than 0.5% by weight of an alkali metal and/or an alkaline earth metal.
Abstract
A process for removing nitrogen oxide from exhaust is disclosed, comprising contacting exhaust containing nitrogen oxide with an alumina catalyst which contains not more than 0.5% by weight of an alkali metal and/or an alkaline earth metal and has a total pore volume of from 0.48 to 1.2 cm 3 ·g -1 with 0.26 to 0.6 cm 3 ·g -1 of the total pore volume being formed of pores of not greater than 80 Å or has a volume of pores formed of pores of not greater than 60 Å of from 0.06 to 0.2 cm 3 ·g -l and which may have supported thereon tin in an oxidative atmosphere containing excess oxygen in the presence of a hydrocarbon or an oxygen-containing organic compound.

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Citations
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Exhaust gas purifying catalyst

TL;DR: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer formed on the substrate using slurry containing a precious metal, alumina, an oxygen storage material and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle size being obtained by observation using a scanning electron microscope as mentioned in this paper.
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References
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Catalysts for selective catalytic reduction denox technology

TL;DR: In this article, a support for selective catalytic reduction of NOx by ammonia is made from porous formed supports having a certain fraction of the pores having pore diameters larger than 600 Angstrom units, and macropores are introduced in a formed TiO₂ support by adding burnout materials or some inorganic oxide prior to forming the titania into the formed support.
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Alumina coating compositions for catalyst supports and process for their formulation

TL;DR: Aqueous alumina coating compositions well adopted for directly impregnating/coating both ceramic and metallic catalyst supports to provide integral, both macroporous and microporous coatings therefor, which coated supports are useful for the fabrication of a wide variety of catalysts for catalyzing a broad spectrum of reactions, including those characterized by highly limited internal diffusion or by progressive catalyst poisoning as discussed by the authors.
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Process for removing nitrogen oxides in exhaust gases to nitrogen

TL;DR: In this paper, a process for reducing nitrogen oxides to nitrogen from exhaust gases is described, which involves bringing an exhaust gas containing nitrogen oxide into contact with at least one catalyst from proton-type zeolites, including metal oxides, by reaction with a hydrocarbon or an oxygen-containing organic compound in an oxidizing atmosphere containing excess oxygen.
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Monolith washcoat having optimum pore structure and optimum method of designing the washcoat

TL;DR: In this paper, an optimum washcoated ceramic monolith for treating automotive exhaust gases is made by specifying the reactants, process conditions and desired time on stream; determining from the parameters in step (a) the pore size distribution and thickness of the washcoat to produce the desired auto exhaust conversion; preparing a washcoat catalyst with an alumina having the desired pore sizes distribution; and applying the prepared washedcoat catalyst to a ceramic or metal monolith to produce a finished automotive exhaust gas catalyst.
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TL;DR: In this paper, 2.2-way and 3-way catalyst compositions comprising tin (IV) oxide (SnO2) and chromium (VI) oxide(CrO3) for use in catalytic converters for vehicle exhaust gas systems, such catalyst compositions being effective in the catalytic oxydation of carbon monoxide and unburnt hydrocarbons, and in the reduction of nitrogen oxides contained in the vehicle exhaust.