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Solar collector comprising transparent hollow plastic microspheres as insulation material

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TLDR
The hollow plastic microspheres as discussed by the authors are made by forming a liquid film of thermoplastic or thermosetting plastic composition across a coaxial blowing nozzle 5, applying a blowing gas 10 at a positive pressure to the inner surface of the plastic film to blow the film and form an elongated cylinder shaped liquid film 12 of plastic.
Abstract
The hollow plastic microspheres 17 are made by forming a liquid film of thermoplastic or thermosetting plastic composition across a coaxial blowing nozzle 5, applying a blowing gas 10 at a positive pressure to the inner surface of the plastic film to blow the film and form an elongated cylinder shaped liquid film 12 of plastic. A transverse jet 13 is used to direct an entraining fluid 14 over and around the blowing nozzle 5, at an angle to the axis of the blowing nozzle. The entraining fluid 14 as it passes over and around the blowing nozzle 5 fluid dynamically induces a pulsating or fluctuating pressure field at the opposite or lee side of the blowing nozzle in the wake or shadow of the coaxial blowing nozzle. The continued movement of the entraining fluid 14 over the elongated cylinder 12 produces asymmetric fluid drag forces on the cylinder and closes and detaches the elongated cylinder from the coaxial blowing nozzle and the detached cylinder by the action of surface tension forms into a spherical shape 17. The hollow plastic microspheres can be made from low heat conductivity plastic compositions and blown with a low heat conductivity gas and used to make improved insulation materials and composites and insulating systems. The hollow plastic microspheres 17 can be made to contain a thin transparent or reflective metal coating 20 deposited on the inner wall surface of the microspheres.

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Citations
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References
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Patent

Method and apparatus for producing concentric hollow spheres

TL;DR: In this paper, a nonconcentric hollow sphere is mass produced by extruding a material such as glass or metal while injecting a stream of gas into the center of the extrusion to form a gas-filled tube.
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Unitary solar collector

TL;DR: A unitary solar collector for transfer of thermal energy is a synthetic thermoplastic unit as mentioned in this paper, which has a solar energy transmitting region and a solar-energy absorbing region, and is useful for heating purposes.
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Method for making small gas-filled beads

TL;DR: In this article, a method and apparatus for making small gas-filled beads by locating a heat deformable tube on top of a heated platen in a controlled atmosphere chamber was described.
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Method for producing small hollow spheres

TL;DR: In this paper, a method for producing small hollow spheres of glass, metal or plastic was proposed, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T ≳ 600°C).
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Solar heating window cover

TL;DR: A dark colored absorbing substrate covered with monolayer of solar radiation, transparent spheres, absorbs solar radiation for heating an air column formed between drapery material and the substrate mounted inside of a transparent window as mentioned in this paper.