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Spectroelectrochemical measurement of chemical reaction rates. First-order catalytic processes

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This article is published in The Journal of Physical Chemistry.The article was published on 1969-01-01. It has received 113 citations till now. The article focuses on the topics: Chemical reaction & Catalysis.

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Homogeneous redox catalysis of electrochemical reactions: Part I. Introduction

TL;DR: In this paper, a detailed kinetic analysis of redox catalysis in the case of an EC-type electrode reaction is given involving the following reaction sequence B → k C A + 1 e ⇌ B B → C } direct electrode reduction of the substrate.
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Study of electrogenerated reactants using optically transparent electrodes

TL;DR: Optically transparent electrodes (OTE) as discussed by the authors have been used for spectroscopic analysis of electrogenerated products for identification or characterization purposes, where the shape of the optical absorbance as a function of time during some electrochemical perturbation can assist in evaluating the mechanism and kinetics of these species.
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Electrocatalysis with ferrocyanide electrostatically trapped in an alkylaminesiloxane polymer film on a Pt electrode

TL;DR: In this paper, a procedure is described whereby thin films of an alkylamine-siloxane polymer can be formed on Pt electrode surfaces, and electrocatalytic reaction of trapped ferrocyanide ions can be stably observed.
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