Journal ArticleDOI
The vibrational ground state rotational spectroscopic constants and structure of the HCN dimer
TLDR
In this article, rotational spectra have been assigned for four isotopic species of the linear HCN dimer in the vibrational ground state, and the spectroscopic constants are isotope - B 0 (MHz) D J (kHz) x N 1 (MHz), x N 2 (MHz).About:
This article is published in Chemical Physics.The article was published on 1981-04-15. It has received 120 citations till now. The article focuses on the topics: Ground state.read more
Citations
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Nonequilibrium Self-Assembly of Long Chains of Polar Molecules in Superfluid Helium
K. Nauta,R. E. Miller +1 more
TL;DR: It is shown that in the low-temperature environment of superfluid helium droplets, long-range dipole-dipole forces acting between two polar molecules can result in the self-assembly of noncovalently bonded linear chains, suggesting a design strategy for the growth of new nanoscale oligomers composed of monomers with defined dipole (or higher order) moment directions.
Journal ArticleDOI
A simple quantitative model of hydrogen-bonding
TL;DR: In this article, a simple model for the computation of intermolecular interactions is described, consisting of atom-atom potentials for the representation of repulsion and dispersion energies, and an evaluation of the electrostatic energy in terms of partitioned multipole moments of the monomer electron distributions.
Journal ArticleDOI
Directional character, strength, and nature of the hydrogen bond in gas-phase dimers
Anthony C. Legon,D. J. Millen +1 more
Journal ArticleDOI
Molecular complexes of the hydrogen halides studied by matrix isolation infrared spectroscopy
TL;DR: Spectroscopic studies of base-hydrogen halide complexes are reviewed in this paper, including previously unpublished data for complexes of hydrogen chloride and hydrogen bromide with a variety of bases in argon matrices.
Journal ArticleDOI
Structure and vibrational dynamics of the CO2 dimer from the sub‐Doppler infrared spectrum of the 2.7 μm Fermi diad
TL;DR: In this paper, the sub-Doppler infrared spectra of two Fermi resonance coupled bands of carbon dioxide dimer have been obtained at 3611.5 and 3713.9 cm−1 using an optothermal molecular beam color center laser spectrometer.
References
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Journal ArticleDOI
Determination of Electronic Structure of Molecules from Nuclear Quadrupole Effects
TL;DR: In this article, it was shown that this variation of electric field is usually simply related to the molecular electronic structure, being primarily dependent on the way in which valence electrons fill the lowest energy p-type orbits.
Journal ArticleDOI
Radiofrequency and Microwave Spectrum of the Hydrogen Fluoride Dimer; a Nonrigid Molecule
TL;DR: In this paper, the radiofrequency and microwave spectra of the K = 0 states of (HF)2, (DF)2 and (HFDF) have been studied by the molecular beam electric resonance method.
Journal ArticleDOI
A new method for observing the rotational spectra of weak molecular complexes: KrHCl
TL;DR: In this article, the rotational transitions of weak molecular complexes were observed by combining the techniques of microwave Fourier transform spectroscopy, a Fabry-Perot cavity, and a pulsed nozzle source of molecules.
Journal ArticleDOI
Hydrogen bonding: The structure of HF–HCl
TL;DR: The structure of the hydrogen-cluster complex formed between HF and HCl has been determined by molecular beam electric resonance spectroscopy as discussed by the authors, and the equilibrium atomic arrangement is HF-HCl with the internal proton colinear with the two heavy atoms spaced 2.12 A from the fluorine atom.
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