Patent
Thermo- and active energy beam-setting resin composition used for protective layer of transfer material, transfer material, surface protecting material, and process for producing molded product of high abrasion resistance and high chemical resistance
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TLDR
In this paper, a sheet material the protective layer of which is made of a thermal reactant of a thermo-and active energy line-setting resin composition containing as effective components a polymer having a (meth)acrylic equivalent of 100-300 g/eq, a hydroxyl group value of 20-500 and a weight average molecular weight of 5,000-50,000, and multifunctional isocyanate.Abstract:
A sheet material the protective layer of which is made of a thermal reactant of a thermo- and active energy line-setting resin composition containing as effective components a polymer having a (meth)acrylic equivalent of 100-300 g/eq, a hydroxyl group value of 20-500 and a weight average molecular weight of 5,000-50,000, and multifunctional isocyanate. The protective layer provided on the surface of a molded product is cured by the irradiation with an active energy beam. Accordingly, a molded product having a high abrasion resistance and a high chemical resistance is obtained, and cracks do not occur in curved surface portions thereof. Since the protective layer is semi-cured thermally during the production of the sheet material, a large apparatus for applying an active energy beam to the protective layer is unnecessary, and the manufacturing cost decreases.read more
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Transfer material, surface-protective sheet, and process for producing molded article with these
TL;DR: In this paper, a transfer material comprising a releasable base sheet and a protective layer formed on one side of the base sheet, characterized in that the protective layer comprises a cured resin obtained by thermally crosslinking a resin composition curable with heat and actinic energy rays comprising as the active ingredients a polymer having a (meth)acrylic equivalent of 100 to 300 g/eq, a hydroxyl value of 20 to 500, and a weight-average molecular weight of 5,000 to 50,000, a polyfunctional isocyanate, and an ultraviolet
Patent
Production of a three-dimensional molding
Klaus Müller,Klaus Klemm +1 more
TL;DR: In this paper, a process for producing a three-dimensional molding made from a layered composite material comprising a thermoplastic polymer backing, an intermediate layer arranged thereupon and a heat-cured layer applied to the intermediate layer comprises bonding the intermediate layers and the heat cured layer applied by heat treatment in a molding system.
Patent
Sheet for forming hard coating
TL;DR: In this article, a sheet for forming a hard coating and a method of formation is described. But the method is not described in detail, except that it is based on a transfer material or a surface protection sheet having a high index of refraction and superior physical properties.
Patent
Process for production of transfer sheets excellent in the resistance to burr generation and transfer sheets
TL;DR: In this article, a process for the production of a transfer sheet provided with a protective layer which is more excellent in resistance to burr generation and in wear resistance and which is also excellent in the ability to follow the curved surface of a substrate is described.
Patent
Method for molding a three dimensional product
Klaus Klemm,Klaus Müller +1 more
TL;DR: In this article, a thermoplastic carrier layer and a laminate based on an intermediate layer and heat-cured layer are combined in a tool using heat and may be three-dimensionalally shaped either before or during the joining stage.
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Thermosetting covering sheet and a method of forming hard coating on the surface of substrates using the same
Hiroshi Abe,Akitaka Miyake,Shunro Aoto,Yoshihiro Nishiyama,Morishita Natsuki,Oshikawa Yosuke,Makoto Yamaguchi +6 more
TL;DR: In this paper, a thermosetting covering sheet comprising an unhardened or semihardened layer made of a reactive acrylic resin composition is provided, which is in a solid state at ordinary temperatures, and a blocked isocyanate, the reactive acrylic resin containing a plurality of at least one kind of functional groups selected from the group consisting of hydroxyl, amino, and carboxyl.
Patent
Process for producing propylene resin formed articles with hard coat
TL;DR: In this article, a process for producing a propylene resin formed article with a hard coat is disclosed, comprising forming an ultraviolet-curing acrylic resin coating film on the surface of a polypropylene resin film or sheet, subjecting the sheet with the coating film to thermoforming, and irradiating the film to ultraviolet rays to cure said ultraviolet curing resin, wherein said propylene resin sheet is composed of at least a polyester surface layer containing substantially no nucleating agent on which surface is coated said acrylic resin film and a thermoplastic resin base layer containing a nucleating
Patent
Radiation-sensitive compounds and methods of using same
TL;DR: In this article, a monohydroxylated acrylic monomer with a polyisocyanate is used to create diacrylates, which are then copolymerized with other radiation sensitive materials.
Patent
Urethane resin compositions
Kohji Nasu,Ichiro Minato +1 more
TL;DR: A urethane resin composition which comprises polyisocyanate component having 20/80 to 80/20 of a weight ratio on a solid basis of an α, α-α, α', α'-tetramethyl-xylylene diiscyanate derivative to a hexamethylene diiscynate derivative and an acrylic polyol is described in this article.
Patent
Moulded articles carrying a decorative surfacing film
TL;DR: In this paper, a support is formed by charging the mould cavity with a softened thermoplastic resin, which conforms to the shape of the moulding and consists of a decorative layer and a protective layer of a photopolymerisable resin compsn.