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Water-based pigment ink composition for writing utensil

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TLDR
In this article, the authors proposed a method to obtain a compsn. which is excellent in dispersion stability an hiding power and does not require operations such as stirring before the use by fixing fine titanium oxide particles on the surfaces of resin particles to form composite particles with specified particle sizes.
Abstract
PURPOSE:To obtain a compsn. which is excellent in dispersion stability an hiding power and does not require operations such as stirring before the use by fixing fine titanium oxide particles on the surfaces of resin particles to form composite particles with specified particle sizes. CONSTITUTION:The compsn. contains, as a coloring matter, composite particle having a mean particle size of 0.2-2mum and obtd. by fixing fine titanium oxide particles having a mean particle size of 0.1mum or lower on the surfaces of resin particles. The resin particle reduces the apparent density of the oxide particles, improving the dispersion stability of the latter particles, and increases the apparent particle size of the latter, improving the whiteness and hiding power of the latter. The composite particles are obtd. by mixing the resin and the oxide particles and fixing the oxide particles on the surfaces of the resin particles by causing the oxide particles to be adsorbed by the surface or to be forced into the resin particles, e.g. by mixing and grinding with an automatic mortar, a jet mill, etc., and/or giving a mechanical impact with a hammer mill, etc.

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Patent

Preparation process of white pigment for water-based inks

TL;DR: In this paper, the white pigment for the water-base ink comprises core particles comprising a material having a smaller specific gravity than that of titanium oxide and a titanium oxide layer with which the surface of the core particles is coated, and has a particle diameter of 0.05-5 μm.
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White pigment for aqueous ink and ink composition using the same

TL;DR: In this article, the white pigment for an aqueous ink comprises a core particle composed of a material having a specific gravity less than that of titanium oxide and a titanium oxide layer applied on the surface of the core particle, and the particle diameter of the pigment is 0.05-5 μm.
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TL;DR: In this paper, an organic-inorganic composite consisting of disposed organic polymer particles having a 50% volume particle diameter of 10 to 300 nm and dispersible into an aqueous medium in a matrix mainly consisting of a metal oxide whose refractive index in a wavelength of 589.3 nm (Na-D line) is ≥ 1.8.
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Ink composition for writing tool

TL;DR: In this paper, a microcapsule particle encapsulating a dispersion where an opacifying particle and a structural viscosity-imparting agent are dispersed in a solvent is employed.