How is lactic acid formed?4 answersLactic acid is formed through various processes such as condensation reactions, fermentation, and bioconversion. In condensation reactions, lactic acid is synthesized through dehydration at high temperature under catalysis. Fermentation is another method where lactic acid is produced by fermenting sugars obtained from renewable resources. This process involves cultivating strains of bacteria or yeast capable of yielding lactic acid by consuming sugars in a seed medium and fermenting the biomass-based material with the seed culture. Bioconversion is also used to produce lactic acid from whey by-products rich in lactose and minerals. This method involves neutralizing the whey by-product, fermenting it with a bacterium capable of converting lactose to lactic acid, and then acidifying the fermentation broth to release lactic acid.
How is citric acid made?4 answersCitric acid is produced through fermentation using filamentous fungi, particularly Aspergillus species. These fungi, such as Aspergillus niger and Aspergillus flavus, are commonly used for citric acid production. The fermentation process involves the use of low-cost substrates like wheat flour, corn starch, and sweet potato, which are fermented by the fungi to synthesize citric acid. Factors such as substrate concentration, incubation time, temperature, and pH are optimized to achieve maximum citric acid yield. The production of citric acid can be carried out using different fermentation techniques, including submerged fermentation, solid-state fermentation, and surface fermentation. The use of novel technologies like gene editing and synthetic biology is being explored to improve the efficiency and sustainability of citric acid production. Overall, citric acid production involves the cultivation of Aspergillus fungi on suitable substrates under optimized conditions to achieve high yields of this important organic acid.
How to produce lactic acid?4 answersLactic acid can be produced through various methods, including microbial fermentation and chemical synthesis. Microbial fermentation involves the use of bacteria, fungi, yeast, and algae to convert sugars obtained from renewable resources into lactic acid. This method produces optically pure forms of lactic acid, eliminating the need for further purification. On the other hand, chemically synthesized lactic acid is typically a racemic mixture of D- and L-lactic acid, which requires purification for use in industries such as pharmaceuticals and food. The use of renewable resources, such as lignocellulosic biomass and organic waste, as feedstock for microbial fermentation not only helps in waste management but also reduces production costs. Pretreatment methods are employed to hydrolyze lignocellulosic materials into sugar-rich feedstocks for fermentation. The fermentation process involves the conversion of sugars to lactic acid by fermentative lactic acid bacteria. Industrial production and purification of lactic acid can be achieved through continuous simultaneous saccharification and fermentation coupled with membrane-based separation, which improves concentration, productivity, and yield.
How to make sulfuric acid?4 answersSulfuric acid can be produced through various methods. One method involves oxidizing sulfur to sulfur dioxide using dried air, followed by oxidizing sulfur dioxide to sulfur trioxide, which is then absorbed by sulfuric acid in an absorption stage. Heated sulfuric acid can be drawn off from the absorption stage for steam generation. Another method involves electrolysis, where a sulfuric acid solution containing chloride ions is fed into an electrolysis vessel, and a metal-melted electrolytic solution is taken out from the anode chamber, resulting in high-quality sulfuric acid production. A different method involves catalytic conversion of a feed gas containing SO2 into SO3, followed by cooling, heating, and wet condensation to extract a concentrated sulfuric acid product stream. Yet another method involves burning a hydrogen sulfide-containing gas, cooling it, and subjecting it to two-step conversion in the presence of a vanadium oxide catalyst, resulting in the production of sulfuric acid. Additionally, sulfuric acid can be produced from waste sulfuric acid by reacting it with lime powder or limestone flour, followed by catalytic oxidation and absorption.
How is prechloric acid produced from hydrochloric acid in industry?3 answersPrechloric acid is produced from hydrochloric acid in industry through various methods. One method involves vacuum purification, where industrial hydrochloric acid is added to a distiller and heated to boil. The hydrogen chloride gas is then condensed and absorbed to obtain low concentration acid, which is further processed to increase the concentration of hydrogen chloride. When the concentration reaches more than 36%, the hydrochloric acid is subpackaged and stored. Another method involves ion separation, where dilute hydrochloric acid is separated into liquid concentrated hydrochloric acid and vaporized hydrochloric acid. The vaporized hydrochloric acid is then removed through condensation, while the dilute hydrochloric acid is regenerated. Additionally, hydrochloric acid can be produced by capturing hydrogen chloride from exhaust gas and removing iron ions through refinery columns. Furthermore, hydrochloric acid can be prepared as a by-product through tail gas absorption in chloroacetic acid production process. Finally, hydrochloric acid-containing waste liquid can be regenerated through microwave heating and condensation.
How to synthesize acyl chloride from carboxylic acid?5 answersAcyl chloride can be synthesized from carboxylic acid using various methods. One method involves adding carboxylic acid into a reactor, introducing phosgene for a reaction, and then purifying the reaction liquid through decompression distillation to obtain the desired acyl chloride. Another method utilizes an immobilized catalyst, where the catalyst is added to the carboxylic acid or its dissolved form in an organic solvent, and an acylating agent is added to react at a specific temperature. The immobilized catalyst can be recovered and reused, making it more suitable for industrial production. Additionally, acyl chloride can be prepared by catalyzing phosgene and acid, where carboxylic acid, a catalyst, and a solvent are added, and phosgene is introduced into a reaction flask. The resulting mixture is then filtered and subjected to reduced pressure distillation to obtain acyl chloride. Another method involves reacting acyl chlorides with hydroxylamine hydrochloride and NaHCO3 in ethyl acetate and water at room temperature to generate hydroxamic acid products. Lastly, a synthesis method uses tertiary amine compounds and dichloromethyl (trichloromethyl) carbonate to obtain acyl chloride compounds.