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How to measure glass transition temperature of propellants? 


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The glass transition temperature of propellants can be measured using Dynamic Mechanical Analysis (DMA). DMA involves subjecting the propellant to varying temperatures and measuring parameters like storage modulus E', loss modulus E", and tanδ to determine the glass transition temperature. In the case of solid rocket propellants, the glass transition temperature is crucial for safe operation and storage. Additionally, machine learning models have been developed to predict the glass transition temperature of organic compounds, including propellants, based on input variables derived from molecular structures. Understanding the glass transition temperature is essential for assessing the propellant's behavior under different conditions and ensuring its stability and performance. Molecular dynamics simulations have also been utilized to forecast the glass transition temperature of propellants like hydroxyl terminated polybutadiene (HTPB).

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The glass transition temperature of propellants can be measured using dynamic mechanical analysis (DMA) to analyze the material's transition from a glassy to a rubbery state.
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The paper describes using Dynamic Mechanical Analysis (DMA) to measure the glass transition temperature of double-base rocket propellants.
The glass transition temperature of propellants can be measured by using a DMA analyzer with dual-cantilever testing mode, heating the propellants at a rate of 2K/min in the temperature range from -120 °C to 110 °C. The glass transition is determined from the peak of the loss modulus curve.

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What is Glass Transition Temperature?4 answersThe glass transition temperature (Tg) is a fundamental property of polymers that describes their behavior. It is the temperature at which a polymer transitions from a rigid, glassy state to a more flexible, rubbery state. Tg is an important characteristic because it affects the material's mechanical, thermal, and electrical properties. Different techniques can be used to determine Tg, such as differential scanning calorimetry and low-frequency Raman spectroscopy. Raman spectroscopy is a promising technique for thermal characterization of polymers because it is chemically agnostic, contactless, and does not require intensity calibration or deconvolution.The glass transition of polymers can be characterized by changes in the probability distribution of dihedral angles and the distribution of time spent in different torsional states. These molecular signatures provide insights into the spatial heterogeneity and dynamical ergodicity breaking in polymer systems, and can help quantitatively determine the transition temperature.
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