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What is rate of reaction? 


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The rate of reaction is defined as the change in the number of molecules of reacting species per unit volume per unit time. It is crucial in determining the speed at which a chemical reaction occurs. Experimental measurements involve rates of reactant consumption or product formation, which are distinct from reaction rates. The rate of a chemical reaction is influenced by factors such as reactants, products, and temperature. The rate law of a reaction, expressed as a differential equation, describes the rate of change of reactant or product concentration over time. Understanding the rate of reaction is essential for studying kinetics and determining the mechanisms of chemical reactions. The rate constant, obtained from experimental data, provides insights into the relationship between reactant concentration and reaction rate.

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Book ChapterDOI
01 Jan 2000
38 Citations
The rate of a chemical reaction is determined by the reactants, products, and temperature. It is described by the rate law, which is the differential equation for concentration change over time.
The rate of reaction is the molar rate of generation per unit volume of a species through a reaction step, as defined in the paper's framework of physicochemical phenomena.
A reaction rate is a property of a specific reaction, not of chemical species. It is defined as (dξ/dt)/V in a homogeneous closed reactor, with variations in open systems.
Journal ArticleDOI
Rate of reaction refers to the speed at which a chemical reaction takes place. The Glossary provides definitions and explanations related to physical organic chemistry terms, including those associated with reaction rates.
Rate of reaction is the change in the number of reacting molecules per unit volume per unit time. It can be influenced by concentration, as seen in the hydrolysis of ethyl acetate.

Related Questions

How does the rate of nuclear reactions work?5 answersThe rate of nuclear reactions is crucial in astrophysics and chemistry. In stellar environments like white dwarfs, nuclear reactions occur at rates influenced by the Coulomb energies between nuclei and their motion within the lattice structure. These rates are determined by factors like nuclear level density, cross sections, and velocity over energy integration. Understanding the Q value of a reaction categorizes it as endothermic or exothermic, impacting the reaction rate. In astrophysics, reaction rates are essential for nucleosynthesis and energy generation, with reciprocity relations ensuring numerical stability and equilibrium abundances at high temperatures. Chemical reaction rates are defined by stoichiometric numbers and concentrations of transformations per unit volume, providing insights into reaction kinetics. Overall, nuclear reaction rates are influenced by various factors and play a fundamental role in both astrophysical and chemical processes.
What are the factors that affect the reaction rate?5 answersThe factors that affect the reaction rate include temperature, concentration of reactants, and the presence of catalysts or enzymes. Increasing the temperature, partial pressure, or concentration of reactants increases the probability of collision rate between molecules, leading to an increase in the reaction rate. Catalysts and enzymes provide alternate reaction paths that lower the activation energy barrier, also increasing the reaction rate. Additionally, the deformability of the substrate on which the reaction occurs can affect the reaction rate. For example, surface tension-driven deformation of a solid can increase the reaction rate by diminishing the activation energy barrier. Other factors such as molecular characteristics of reactants and catalysts, solvent properties, mass transfer limitations, and external potentials or forces can also influence the reaction rate.
What is reaction rate constant?4 answersThe reaction rate constant is a parameter that characterizes the speed at which a chemical reaction takes place. It is a crucial factor in determining the efficiency of acid treatments and studying the kinetics of reactions. In the field of cytometry, the reaction rate constant is used to study the heterogeneity of cell populations and the activity of cellular reactions. By following the conversion of a reaction substrate into a product over time, the reaction rate constant can be determined for individual cells, allowing for the analysis of cell-population heterogeneity. In the context of mathematical modeling, the reaction rate constant is used to describe the kinetics of multicomponent reaction systems, such as diesel fuel hydrotreating. Additionally, the reaction rate constant is computed for the radiative association of carbon cations and fluorine atoms, providing insights into the rate of this chemical reaction.
What is reaction kinetics?5 answersReaction kinetics is the study of how chemical reactions occur and the factors that influence their rates. It involves understanding the changes that happen over time in natural phenomena, such as the origins of the world and the characteristics of quantum mechanics, classical mechanics, and thermodynamics. Chemical kinetics, a branch of chemistry, focuses on the rates of chemical reactions and their relationship to reactant concentrations and temperature. It also involves mathematical modeling of these reactions, including enzyme processes, using techniques like flow charts and ordinary differential equations. Reaction kinetics is important in fields like chemical engineering, where it helps translate laboratory-scale studies to large-scale reactor conditions. The determination of kinetic parameters, such as activation energy and reaction models, can be done using various methods, including model-fitting and model-free approaches. Overall, reaction kinetics provides a theoretical framework for understanding and predicting the behavior of chemical reactions in different systems and conditions.
What does rate mean in programming language?5 answersThe term "rate" in programming language can have different meanings depending on the context. In the context of data collection and analysis, the term "rate" refers to a system or program called RATE that is used for coding and recording data during observations or experiments. This system allows for the collection of ethnographic or quality data, and can be synchronized with audio or video recordings for review or debriefing purposes. In the context of reconfigurable architectures, the term "rate" is used in the Reconfigurable Architecture TEsting Suite (RATES), which defines a standard for describing and using benchmarks for reconfigurable architectures. Finally, in the context of real-time task scheduling, the term "rate" is used in the rate-monotonic algorithm, which is a popular algorithm for scheduling periodic tasks on multiprocessor platforms.
What factors affect the rate of a reaction?4 answersThe rate of a reaction can be affected by several factors. Firstly, the nature of the reactants plays a role in determining reaction velocities. Secondly, the concentration of reagents, as well as the concentration of products in reversible reactions, also affect reaction rates. Temperature is another important factor, as reaction rates depend on the rate constant and the exponential term related to temperature. Light can also influence reaction rates, as seen in processes like photosynthesis and photography. Catalysts, on the other hand, do not alter the position of equilibrium but provide a pathway with lower activation energy for the reactants, thereby affecting reaction rates. In addition to these factors, the size of the cavity, the conformation of the reactive group, and the hydrogen bond of the reactive group with neighboring molecules can also impact reaction rates.

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