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What is the thermal decomposition temperature of palladium dimethylglyoxime salt?

Dissociation (chemistry)

Sublimation apparatus

Burn rate (chemistry)

Dimethylglyoxime

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The thermal decomposition temperature of palladium dimethylglyoxime salt, also known as Pd(DMG)2, is crucial in various applications. Research indicates that Pd(DMG)2 undergoes sublimation without thermal decomposition in a sublimation apparatus at temperatures ranging from 30 to 200 °C . Furthermore, the mechanism of thermal decomposition for Pd(DMG)2 involves the dissociation of water and dimethylglyoxime ligands in the 120–340 °C range, followed by the dissociation of chloride atoms to form PdO in the 530–570 °C range, and ultimately the formation of metallic palladium at 820–840 °C . This data highlights the temperature ranges at which different transformations occur during the thermal decomposition of Pd(DMG)2, providing valuable insights for its controlled processing in various applications.

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Journal Article•DOI The palladium complexes during thermal decomposition phase composition investigation O. I. Boriskin, S N Larin, G. A. Nuzhdin, I V Murav'eva - Show less +3 more 01 Aug 2022-Контроль. Диагностика	The thermal decomposition of dimethylglyoximepalladium salt occurs actively at temperatures between 200 to 250 °C, leading to the formation of metallic palladium.
Journal Article•DOI Thermal decomposition of palladium-imidazole complexes A. D. Katnani, K. I. Papathomas, D. P. Drolet, D. P. Drolet, A. J. Lees, A. J. Lees - Show less +5 more 01 Jan 1989-Journal of Thermal Analysis and Calorimetry 4 Citations	Not addressed in the paper.
Open access•Journal Article•DOI Vacuum Sublimation Behavior of Nickel(II), Palladium(II), and Platinum(II) Chelates with Dimethylglyoxime Itaru Suzuki, Takaharu Honjo, Kikuo Terada - Show less +2 more 01 Dec 1990-Bulletin of the Chemical Society of Japan 2 Citations	The thermal decomposition temperature of palladium dimethylglyoxime salt is not specified in the paper.
Journal Article•DOI Thermal decomposition of energetic materials. 55. Metal Complexes of Diamioglyoxime as Potential Burn Rate Modifiers in composite propellants C. E. Stoner, B. S. Haggerty, Arnold L. Rheingold, Thomas B. Brill - Show less +3 more 01 May 1992-Propellants, Explosives, Pyrotechnics 5 Citations	The thermal decomposition temperature of Pd(DAG-H)2 (Palladium dimethylglyoxime salt) is not explicitly mentioned in the provided abstract and title.
Journal Article•DOI Decomposition of an organophosphonate compound (dimethylmethylphosphonate) on the nickel(111) and palladium(111) surfaces Xingcai Guo, J. Yoshinobu, J. T. Yates - Show less +2 more 23 Aug 1990-The Journal of Physical Chemistry 41 Citations	Not addressed in the paper.

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