Showing papers on "Benzoylurea published in 2021"
TL;DR: In this article, a magnetic covalent organic framework (NH2-Fe3O4@COF) was prepared using a simple room-temperature synthesis in order to obtain high adsorption performance for six benzoylurea insecticides.
28 citations
TL;DR: Comparative studies of the effects of three compounds conducted on Spodoptera littoralis found N-(2-cyanoacetyl)hydrazinecarbonothioyl)furan-2-carboxamide (3) is more active than the other compounds, which caused larval mortality proportional to the concentrations in the food source.
Abstract: Due to the complicated problems coming from excessive applications of insecticides, searching for safe substitutes to these insecticides has become a necessity. Thus, the insect growth regulators are candidates to be used in such concern. Comparative studies of the effects of three compounds, 2-benzoyl-N-phenylhydrazine-1-carbothioamide (1), 2-(cyanoacetyl)-N-phenylhydrazine-1-carboxamide (2) and N-(2-(2-cyanoacetyl)hydrazinecarbonothioyl)furan-2-carboxamide (3) (an insect growth regulator inhibiting chitin synthesis), were conducted on Spodoptera littoralis (Boisduval, 1833). The compounds, orally administered, caused larval mortality proportional to the concentrations in the food source. larvae were unable to complete the molting process and died in the old larval cuticle. Larvae contaminated by sublethal doses completed their development to adulthood. N-(2-(2-cyanoacetyl)hydrazinecarbonothioyl)furan-2-carboxamide (3) is more active than the other compounds have LC50 17.082 ppm for 2nd instar larvae and 60.832 ppm for 4th instar larvae.
16 citations
TL;DR: Flufenoxuron is a benzoylurea pesticide that is used to eradicate insects and acarids in the farmland as discussed by the authors, however, the reproductive toxicity and cellular mechanisms of flufenoxuron have not been identified.
8 citations
TL;DR: In this article, a co-precipitation method was developed for preconcentrating and simultaneous analysis of six benzoylurea insecticides (BUs) by high-performance liquid chromatography (HPLC).
Abstract: Layered-double hydroxides (LDHs) modified with anionic surfactants via a co-precipitation method were developed for preconcentrating and simultaneous analysis of six benzoylurea insecticides (BUs) by high-performance liquid chromatography (HPLC). The anionic surfactants with different chain lengths, including sodium dodecylbenzene sulfonate (SDBS), sodium dodecyl sulfate (SDS), sodium 1-nonane sulfonate (SNS), and sodium 1-hexane sulfonate monohydrate (SHS) were investigated to improve the extraction efficiency of LDHs. The SDBS-LDHs provided the highest efficiency for the enrichment of the BUs studied. Under the chosen conditions, enrichment factors in the range of 38-69 and detection limits in the range of 0.1-0.3 μg L-1 were achieved. Good reproducibilities (RSD < 13.8%) and recoveries (71.4-118.7%) were also obtained. The proposed preconcentration method, used as an in situ procedure offers rapid and simple simultaneous preparation of LDHs and extraction of BUs. The method was successfully applied for residue analysis of BUs in fruit- and flower-derived soft drink samples.
4 citations
TL;DR: In this article, a novel method using a phosphonium-based deep eutectic solvent coupled with vortex-assisted liquid-liquid microextraction was investigated for the enrichment and separation of five benzoylurea insecticides in olive oil.
Abstract: In this study, a novel method using a phosphonium-based deep eutectic solvent coupled with vortex-assisted liquid-liquid microextraction was investigated for the enrichment and separation of five benzoylurea insecticides in olive oil. The experimental factors affecting the extraction efficiency, including the extractant type, deep eutectic solvent volume, extraction time, and extraction mode, were optimized. Under optimal conditions, good linearity was observed for all target analytes, with correlation coefficients (r) ranging from 0.9971 to 0.9998; the limits of detection were in the range of 1.5 to 7.5 μg/L, and the recoveries of analytes using the proposed method ranged between 66.9 and 111.0%. The simple, rapid, and effective method was successfully applied for detecting target analytes in olive oil sample.
4 citations
TL;DR: In this article, a novel hyperbranched aromatic polyamide-coated magnetic sorbent was prepared by in situ polymerization on the surface of amino-functionalized Fe3 O4 nanoparticles.
Abstract: Herein, a novel hyperbranched aromatic polyamide-coated magnetic sorbent was prepared by in situ polymerization on the surface of amino-functionalized Fe3 O4 nanoparticles. The magnetic sorbent was characterized by transmission electron microscopy, Fourier transform infrared spectroscopy, elemental analysis, Brunauer-Emmett-Teller measurement, and X-ray photoelectron spectroscopy, etc. The new magnetic sorbent was used in the magnetic solid-phase extraction for the detection of seven benzoylurea insecticides. Under optimum conditions, low method detection limits (0.56-1.20 ng/mL), acceptable coefficient of determination (0.9967-0.9996), wide linear ranges (2.5-500.0 ng/mL), and good repeatability (intraday: 2.0-7.3%; interday: 1.9-9.2%) were achieved. The magnetic solid-phase extraction method based on the new magnetic sorbent showed good reliability in the analysis of seven benzoylurea insecticides in real water samples, as the relative recoveries were in the range from 80.1 to 116.3% with satisfactory RSDs (0.1-9.8%). By means of density functional theory and semiempirical quantum mechanical, the binding configuration and interaction energy of hyperbranched aromatic polyamide and benzoylurea insecticides were calculated. The result of theoretical calculation revealed that the adsorption of benzoylurea insecticides by hyperbranched aromatic polyamide was derived from hydrogen bonding and π-π stacking. The contribution of π-π stacking was greater than that of hydrogen bond, which was confirmed by energy decomposition analysis.
2 citations