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Showing papers on "Conductive polymer published in 1978"


Patent
13 Mar 1978
TL;DR: A laminar triplex structure for use in the manufacture of electrical cells and batteries, cells and battery made therefrom, and methods of making the same is described in this paper.
Abstract: A laminar triplex structure for use in the manufacture of electrical cells and batteries, cells and batteries made therefrom, and methods of making the same. The laminate comprises a thin flat sheet of separator material, a layer of metallic particles on one surface of the separator sheet and adhered thereto with a binder, and a layer of conductive plastic adhered to the layer of metal particles. The laminate is made by the process of coating a dispersion of metal particles in a solution of a polymeric binder in an organic solvent over the separator, drying to remove the solvent, coating over the dried metal layer with a dispersion of conductive particles in a solution of a polymer in an organic solvent, and drying to remove the solvent.

58 citations


Patent
03 Nov 1978
TL;DR: In this article, a fluorine-containing peroxide, such as FSO2 --O--O--SO2 F, is used to obtain a metal-like conductivity at temperatures above about 150° K, and specific conductivities above about 102 ohm-1 -cm-1 at room temperature.
Abstract: Electrically conducting polyacetylene compositions are described having incorporated therein a fluorine-containing peroxide, such as FSO2 --O--O--SO2 F. Preferred compositions exhibit novel metal-like conductivity at temperatures above about 150° K., and specific conductivities above about 102 ohm-1 -cm-1 at room temperature, as measured by the standard four-probe method. A process for producing the compositions is also described in which polyacetylene is contacted with the peroxide, preferably in an inert liquid solvent at low temperatures.

19 citations


Journal ArticleDOI
TL;DR: In this article, the synthesis and properties of phenylene- and biphenyl-bridged polymer tetrathiafulvalenes are described, and the conductivity depends on stoichiometric composition of the radicale-salts.
Abstract: Conductive Polymers with Tetrathiafulvalene Structure Synthesis and properties of phenylene- and biphenyl-bridged polymer tetrathiafulvalenes are described. These polymers react with bromine or iodine and provide the radical-cationhalides, whose electrical conductivity as powder compactions are estimated. The conductivity depends on stoichiometric composition of the radicale-salts. The phenylene-bridged polymer-salts show a much higher conductivity than the biphenyl-bridged ones and reach values of 10−3 ω−1 cm−1. The monomer salts have a higher conductivity than the polymer salts (max. 10−1 Ω−1 cm−1).

18 citations


Patent
20 Oct 1978
TL;DR: The conductive polymer mix as mentioned in this paper is based on the introduction of Silan-chemical compounds, in the presence of moisture, from dampened thermo-plastic materials only, pref. copolymers or ethylene, or thermoplastic material in a mixture of elastomers, as modifiers.
Abstract: The conductive polymer mix, is based on the introduction of Silan-chemical compounds, in the presence of moisture, from dampened thermo-plastic materials only, pref. copolymers or ethylene, or thermo-plastic materials in a mixture of elastomers, as modifiers. In both cases the conductive material is used as an additive. A non hydroscopic carbon-black compound is used as a conductive filler material. An acetylene-carbon is used as a non-hydroscopic carbon. The upper surface is 50-120 m2/g in size. 25-80, pref. 30-50 parts, of the conductive carbon are added, for every 100 parts of polymer. The inner or outer conductive layers consist of a conductive polymer mixture.

4 citations


Patent
13 May 1978
TL;DR: In this article, a stable conductive polymer composition having improved fiber-forming properties, comprising an acrylonitrile polymer, a carbon black-containing antistatic polymer, and a water-insoluble nonionic dispersant, was presented.
Abstract: PURPOSE:A stable conductive polymer composition having improved fiber-forming properties, comprising an acrylonitrile polymer, a carbon black-containing antistatic polymer, and a water-insoluble nonionic dispersant.

1 citations


Book
01 Jan 1978
TL;DR: In this article, the effects of electronic effects on the mechanical properties of Semiconductors have been investigated for the treatment of disordered systems with possible applications to aperiodic polymers.
Abstract: LCAO Methods for Band Structure Calculations of Polymers.- The Evaluation of Electron Repulsion Integrals.- X-ray Photoelectron Spectroscopy and its Application to Polymer Electronic Structure Studies.- Correlation Energy in Solids.- Quantum Mechanical Treatment of Excited Electronic States of Polymers.- Coupled Cluster Many Electron Theory and The Cohesive Energy of Large Systems Consisting of Weakly Interacting Sub-Systems.- Fourier Representation Methods in Electronic Structure Studies of Crystals and Polymers.- Linked-Cluster Perturbation Theory for Closed and Open-Shell Systems: Derivation of Effective It-Electron Hamiltonians.- Methods for The Treatment of Disordered Systems with Possible Applications to Aperiodic Polymers.- Electron States of Structurally-Disordered Chains.- Theoretical Models of Chemisorption of Ions and Small Molecules on Polymers.- Hydrogen Bonding Between Molecules or Ions and in Molecular Crystals.- Electronic Structure of Biopolymers.- Energy Band Structure of Highly Conducting Polymers.- Quantum Mechanical Treatment of Transport Properties of Semiconductors: Possible Application to Polymers.- Quantum Theoretical Treatment of Electronic Effects on The Mechanical Properties of Semiconductors: Possible Application to Polymers.- Theoretical Investigation of The Transport Properties of Polymers and Organic Molecular Crystals.- Index of Authors.

1 citations