Showing papers on "Coordination polymer published in 1977"
TL;DR: Tetracyanomethyl titanium, [Ti(CH2CN)4 · 2 THF]n, can be prepared by reaction of TiCl4 with LiCH 2CN in form of a tetrahydrofuran complex.
Abstract: Tetracyanmethyltitan last sich durch Reaktion von Titan(IV)-chlorid mit Cyanmethyllithium als braune, thermisch recht bestandige, offensichtlich koordinationspolymere Verbindung der Formel [Ti(CH2CN)4 · 2 THF]n gewinnen. Eine nahere Charakterisierung erfolgte mittels des IR- und des 1H-NMR-Spektrums.
Contributions to the Chemistry of Transition Metal Alkyl Compounds. XXV. Preparation and Properties of [Ti(CH2CN)4 · 2 THF]n
Tetracyanomethyl titanium, [Ti(CH2CN)4 · 2 THF]n, can be prepared by reaction of TiCl4 with LiCH2CN in form of a tetrahydrofuran complex. The brown, stable compound, which seems to be a coordination polymer, was characterized by i.r. and 1H-n.m.r. spectra.
10 citations
TL;DR: In this paper, the possibility of using a coordination polymer of chromium(III) with diphenylphosphinic acid as a selective packing for gas chromatography is discussed.
9 citations