Showing papers on "Dichlorophenylphosphine published in 2004"
TL;DR: The Friedel-Crafts reaction of PCl 3 and benzene in [trEHAm]Cl- X AlCl 3 ionic liquids (ILs) was investigated for clean synthesis of dichlorophenylphosphine (DCPP) as discussed by the authors.
Abstract: The Friedel–Crafts reaction of PCl 3 and benzene in [trEHAm]Cl- X AlCl 3 ionic liquids (ILs) was investigated for clean synthesis of dichlorophenylphosphine (DCPP). A simple product isolation procedure was achieved, and the effects of ILs composition, reactant composition, reaction time and quantity of ILs on this reaction were studied. The [trEHAm]Cl- X AlCl 3 ionic liquids gave this reaction a green character. A catalytic mechanism was proposed as well.
17 citations