Influence of molecular size, polarity and charge on the retention of organic molecules by nanofiltration

Mechanisms of retention and flux decline for the nanofiltration of dye baths from the textile industry

Flux decline due to interaction of the membrane with the feed solution is a major drawback for the use of nanofiltration in environmental applications. This paper studies different mechanisms of flux decline for the nanofiltration of aqueous solutions containing organic compounds. The resistance model for flux decline is used: different mechanisms contribute through an increase of the resistance of the membrane against mass transport. The focus in this research is on pore blocking and adsorption inside the membrane pores. Osmotic pressure is also taken into account as it decreases the driving force. The nanofiltration membranes used were NF70 (Dow), UTC-20 and UTC-60 (Toray Ind.), and NTR 7450 (Nitto-Denko). Experiments with different organic components in aqueous solution showed that adsorption resulted in a strong decrease of the water flux. The results of the flux decline as a function of the concentration could well be fitted with the Freundlich equation for adsorption. The components that showed the largest effect had the highest polarity (permanent dipole moment or polarizability), which indicates that adsorption is favored by the polarity of the components in solution. Moreover, the molecules with a size similar to the pore size had a stronger effect on the water flux than other molecules. This can be explained by blocking of the pores by adsorbed compounds.

Flux decline during nanofiltration of organic components in aqueous solution.

Development and characterization of novel charged surface modification macromolecule to polyethersulfone hollow fiber membrane with polyvinylpyrrolidone and water

A.J. Rachwal

Papers

Water treatment for public supply in the 1990's — A role for membrane technology?