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A. Jutand
Researcher at École Normale Supérieure
Publications - 15
Citations - 830
A. Jutand is an academic researcher from École Normale Supérieure. The author has contributed to research in topics: Nucleophile & Aryl. The author has an hindex of 12, co-authored 15 publications receiving 786 citations. Previous affiliations of A. Jutand include Hebrew University of Jerusalem.
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What makes for a good catalytic cycle? A theoretical study of the role of an anionic palladium(0) complex in the cross-coupling of an aryl halide with an anionic nucleophile
TL;DR: In this paper, the authors studied the cross-coupling reaction Ar−X + Nu- → Ar−Nu + X, catalyzed by Pd(0) complexes, theoretically by means of DFT calculations; Ph−Cl was used as a substrate and HS- as the nucleophile.
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Absolute determination of electron consumption in transient or steady state electrochemical techniques
TL;DR: In this paper, a method elaborated from original work by Lingane is discussed and used to determine the absolute value of the electron stoichiometry corresponding to any electrochemical wave, under the exact conditions of its observation.
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Formation of Palladium(0) Complexes from Pd(OAc)2 and a Bidentate Phosphine Ligand (dppp) and Their Reactivity in Oxidative Addition
TL;DR: The oxidative addition of PhI is an intricate reaction whose kinetics has been investigated only in the presence of added AcO-.
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Nanosecond time resolved cyclic voltammetry: Direct observation of electrogenerated intermediates with bimolecular diffusion controlled decay using scan rates in the megavolt per second range
TL;DR: In this article, le mecanisme de dimerisation des radicaux diphenyl-2,6 pyrylium, formes lors de la reduction du cation-parent, is described.
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Decelerating Effect of Alkenes in the Oxidative Addition of Phenyl Iodide to Palladium(0) Complexes in Heck Reactions
TL;DR: In this paper, it was shown that the nucleophile plays a role in the deceleration of the Heck reaction in the presence of an alkene (styrene, methyl acrylate).