http://web.mit.edu/cortiz/www/Jerry/TPU_final.pdf

Stress–strain behavior of thermoplastic polyurethanes

Some fundamental issues in the formulation of constitutive theories of material response based on the multiplicative decomposition of the deformation gradient are reviewed, with focus on finite deformation thermoelasticity, elastoplasticity, and biomechanics. The constitutive theory of isotropic thermoelasticity is first considered. The stress response and the entropy expression are derived in the case of quadratic dependence of the elastic strain energy on the finite elastic strain. Basic kinematic and kinetic aspects of the phenomenological and single crystal elastoplasticity within the framework of the multiplicative decomposition are presented. Attention is given to additive decompositions of the stress and strain rates into their elastic and plastic parts. The constitutive analysis of the stress-modulated growth of pseudo-elastic soft tissues is then presented. The elastic and growth parts of the deformation gradient and the rate of deformation tensor are defined and used to construct the corresponding rate-type biomechanic theory. The structure of the evolution equation for growth-induced stretch ratio is discussed. There are 112 references cited in this review article. DOI: 10.1115/1.1591000 The objective of this survey is to give an overview of the application of the multiplicative decomposition of the deformation gradient in constitutive theories of finite deformation thermoelasticity, elastoplasticity, and biomechanics. The multiplicative decomposition of the deformation gradient is based on an intermediate material configuration, which is obtained by a conceptual destressing of the currently deformed material configuration to zero stress. The significance of such configuration for material modeling was pointed out ˙

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Constitutive theories based on the multiplicative decomposition of deformation gradient: Thermoelasticity, elastoplasticity, and biomechanics

Constitutive modelling in finite thermoviscoplasticity: a physical approach based on nonlinear rheological models

Elastomeric materials experience stretch-induced softening as evidenced by a pre-stretched material exhibiting a significantly more compliant response than that of the virgin material. In this paper, we propose a fully three-dimensional constitutive model for the observed softening of the stress–strain behavior. The model adopts the Mullins and Tobin concept of an evolution in the underlying hard and soft domain microstructure whereby the effective volume fraction of the soft domain increases with stretch. The concept of amplified strain is then utilized in a mapping of the macroscopic deformation to the deformation experienced by the soft domain. The strain energy density function of the material is then determined from the strain energy of the soft domain and thus evolves as the volume fraction of soft domain evolves with deformation. Comparisons of model results for cyclic simple extension with the experimental data of Mullins and Tobin show the efficacy of the model and suggest that an evolution in the underlying soft/hard domain microstructure of the elastomer captures the fundamental features of stretch-induced softening. Model simulations of the cyclic stress–strain behavior and corresponding evolution in structure with strain for uniaxial tension, biaxial tension and plane strain tension are also presented and demonstrate three-dimensional features of the constitutive model.

http://web.mit.edu/cortiz/www/Jerry/jmps_softening.pdf

Constitutive model for stretch-induced softening of the stress?stretch behavior of elastomeric materials

Nonlinear dependence of viscosity in modeling the rate-dependent response of natural and high damping rubbers in compression and shear: Experimental identification and numerical verification

A geometric nonlinear and thermodynamical consistent constitutive theory is proposed, which allows the representation of the thermomechanical behaviour of carbon black filled rubber. In a recent paper [1] it was shown that the mechanical behaviour of this material is mainly influenced by nonlinear elasticity coupled with some inelastic effects, in particular the Mullins-effect, nonlinear rate dependence and a weak equilibrium hysteresis. In the present paper, the Mullins-effect is not taken into consideration. At first we discuss a uniaxial approach, based on a simple spring dashpot system of viscoplasticity. The essential feature of this model is a decomposition of the total stress into a rate independent equilibrium stress and a nonlinear rate dependent overstress. The equilibrium stress is decomposed into a sum of two terms as well: The first term, the elastic part of the equilibrium stress, is a nonlinear function of the total strain, and the second term, the so-called hysteretic part, depends in a rate independent manner on the strain history. Both the overstress and the hysteretic part of the equilibrium stress are determined by nonlinear elasticity relations which depend on internal variables. These internal variables are inelastic strains, and the corresponding evolution equations are developed in consideration of the second law of thermodynamics. Accordingly, we demonstrate that the principle of non-negative dissipation is satisfied for arbitrary deformation processes. In a further step, we transfer the structure of this model to the three-dimensional and geometric nonlinear case. In a certain sense similar to finite deformation elasto-plasticity, we introduce two multiplicative decompositions of the deformation gradient into elastic and inelastic parts. The first decomposition is defined with respect to the overstress and the second one with respect to the hysteretic part of the equilibrium stress. Consequently, two intermediate configurations are induced, which lead two different decompositions of the Green's strain tensor into elastic and inelastic parts. The latter are the internal variables of the model. For physical reasons, we define the corresponding stress tensors and derivatives in the sense of the concept of dual variables [7], [39]. Theconstitutive equations for the overstress and for the hysteretic part of the equilibrium stress are specified by nonlinear elasticity relations, formulated with respect to the different intermediate configurations. In order to facilitate a separate description of inelastic bulk and distortional effects, we introduce kinematic decompositions of the deformation gradient into volumetric and distortional parts. Numerical simulations demonstrate that the developed theory represents the mechanical behaviour of a tread compound at room temperature very well. Thermomechanical heating effects, which are caused by inelastic deformations are also described by the theory. The method proposed in this paper can be utilised to generalise uniaxial rheological models to three-dimensional finite strain theories, which are admissible in the sense of the second law of thermodynamics.

A. Lion

Papers

A physically based method to represent the thermo-mechanical behaviour of elastomers