Over recent years, enthusiasm towards the manufacturing of biopolymers has attracted considerable attention due to the rising concern about depleting resources and worsening pollution. Among the biopolymers available in the world, polylactic acid (PLA) is one of the highest biopolymers produced globally and thus, making it suitable for product commercialisation. Therefore, the effectiveness of natural fibre reinforced PLA composite as an alternative material to substitute the non-renewable petroleum-based materials has been examined by researchers. The type of fibre used in fibre/matrix adhesion is very important because it influences the biocomposites’ mechanical properties. Besides that, an outline of the present circumstance of natural fibre-reinforced PLA 3D printing, as well as its functions in 4D printing for applications of stimuli-responsive polymers were also discussed. This research paper aims to present the development and conducted studies on PLA-based natural fibre bio-composites over the last decade. This work reviews recent PLA-derived bio-composite research related to PLA synthesis and biodegradation, its properties, processes, challenges and prospects.

https://www.mdpi.com/2073-4360/13/8/1326/pdf

Polylactic Acid (PLA) Biocomposite: Processing, Additive Manufacturing and Advanced Applications.

In spite of the fact that a prodigious portion of petroleum covers multitudinous products in the commercial world, its non-biodegradable characteristic is an unenviable factor The utilization of b

https://www.tandfonline.com/doi/pdf/10.1080/24759651.2021.1881214

Biopolymer composites: a review

In this work, fungal melanin was used for the first time to prepare poly(lactic acid)-based composites. The films of various melanin concentrations (0.025%, 0.05% and 0.2% w/w) were prepared using an extrusion method. The mechanical, antioxidant, antimicrobial, water vapor and UV-Vis barrier properties, as well as available polyphenolics on the surface, were studied. FT-IR and Raman spectroscopy studies were carried out to analyze the chemical composition of the resulting films. The hydrophobicity, color response, thermal, optical properties, and opacity values were also determined. The results of this study show that the addition of fungal melanin to poly(lactic acid) (PLA) as a modifier influenced mechanical and water vapor barrier properties depending on melanin concentration. In low concentration, melanin enhanced the mechanical and barrier properties of the modified films, but in larger amounts, the properties were decreased. The UV-Vis barrier properties of PLA/melanin composites were marginally improved. Differential Scanning Calorimetry (DSC) analysis indicated that crystallinity of PLA increased by the addition of melanin, but this did not affect the thermal stability of the films. Modified PLA/melanin films showed good antioxidant activity and were active against Enterococcus faecalis, Pseudomonas aeruginosa and Pseudomonas putida. The addition of melanin caused changes in color values, decreasing lightness and increasing the redness and yellowness of films. Based on the results of this study, fungal melanin has good potential to be exploited as a value-added modifier that can improve the overall properties of PLA.

New Poly(lactic acid) Active Packaging Composite Films Incorporated with Fungal Melanin.

Plant leaf-mimetic smart wind turbine blades by 4D printing

Accelerated weathering and soil burial effects on colour, biodegradability and thermal properties of bamboo/kenaf/epoxy hybrid composites

Developing an eco-friendly industry based on green materials, sustainable technologies, and optimum processes with low environmental impact is a general societal goal, but this remains a considerable challenge to achieve. Despite the large number of research on green structural composites, limited investigation into the most appropriate manufacturing methodology to develop a structural material at industrial level has taken place. Laboratory panels have been manufactured with different natural fibers but the methodologies and values obtained could not be extrapolated at industrial level. Bamboo industry panels have increased in the secondary structural sector such as building application, flooring and sport device, because it is one of the cheapest raw materials. At industrial level, the panels are manufactured with only the inner and intermediate region of the bamboo culm. However, it has been found that the mechanical properties of the external shells of bamboo culm are much better than the average cross-sectional properties. Thin strips of bamboo (1.5 mm thick and 1500 mm long) were machined and arranged with the desired lay-up and shape to obtain laminates with specific properties better than those of conventional E-Glass/Epoxy laminates in terms of both strength and stiffness. The strips of bamboo were bonded together by a natural thermoplastic polylactic acid (PLA) matrix to meet biodegradability requirements. The innovative mechanical extraction process developed in this study can extract natural strip reinforcements with high performance, low cost, and high rate, with no negative environmental impact, as no chemical treatments are used. The process can be performed at the industrial level. Furthermore, in order to validate the structural applications of the composite, the mechanical properties were analyzed under ageing conditions. This material could satisfy the requirements for adequate mechanical properties and life cycle costs at industrial sectors such as energy or automotive.

Bamboo–Polylactic Acid (PLA) Composite Material for Structural Applications

Tests on a double lap bonded joint, with transverse strips of randomly oriented carbon nanotubes (CNT) sprayed onto an epoxy adhesive film, showed a positive increment in electrical resistance under tensile load, even though the transverse strains were negative. Other experiments included in this work involved placing longitudinal and transversal CNT sensors in a tensile loaded aluminum plate, and, as reported by other authors, the results confirm that the resistance change is not only dependent on the strains oriented with the electrode line, while the other strain components also influence the response. This behavior is quite different to that of conventional strain gages which have a near zero sensitivity to strains not aligned to the sensor direction. The dependence of the electrical response on all the strain components makes it quite difficult, possibly unfeasible, to experimentally determine the individual strain components with this kind of sensors; however, the manufacturing of aligned CNT sensors could deal with this issue.

https://www.mdpi.com/1424-8220/20/10/2980/pdf

Directional Response of Randomly Dispersed Carbon Nanotube Strain Sensors.

Les AA presentent les recherches effectuees par l'expedition americano-daghestanaise de 1997 a 1999 dans la region bordant la mer Caspienne, au Daghestan, et sur les sites de Velikent et de Kabaz-Kutan en particulier. Les structures domestiques et funeraires (tertres, pithouses...) du Chalcolithique final et du debut de l'âge du Bronze ont revele de nombreuses pieces de mobilier (ceramique, industries lithique, osseuse, metallique...). Les AA proposent egalement une description des restes d'animaux.

A. Morales

Papers

Bamboo–Polylactic Acid (PLA) Composite Material for Structural Applications

Directional Response of Randomly Dispersed Carbon Nanotube Strain Sensors.

Daghestan-american archaeological investigations in Daghestan, Russia 1997-99