Electrospray mass spectrometry applied to inorganic and organometallic chemistry

Synthesis, structure and reactions of [(BuSn)12O14(OH)6]Cl2 · 2H2O: Solution studies using 119Sn NMR and electrospray mass spectrometry

Electrospray mass spectrometry: a tool for elemental speciation

Analysis of organometallic compounds using ion trap mass spectrometry

https://link.springer.com/content/pdf/10.1016/1044-0305(94)80007-3.pdf

Ion spray-tandem mass spectrometry of supramolecular coordination complexes

Electrospray mass spectrometric (ESMS) studies have been made on some representative examples of the trinuclear complexes [M 3 O(RCOO) 6 (H 2 O) 3 ] + (M=Cr, Fe; R=H, CH 3 , CH 3 CH 2 , (CH 3 ) 3 C) in methanol and pyridine/ methanol solutions. The nonbridging water ligands in the Cr(III) complexes partially exchange with the solvent molecules and ions containing the central Cr 3 O(RCOO) 6 core, and various combinations of terminal ligand are observed. At low first skimmer voltages, intact ions with three terminal ligands are detected, but as the skimmer voltage is increased, interaction with solvent molecules within the ion sourcecauses collisionally activated decompositions to occur, leading to progressive loss of the labile terminal groups

Adrian van den Bergen

Papers

Electrospray mass spectrometric study of [M3O(RCOO)6L3]+ cations (M = chromium, iron; L = H2O, MeOH, py)

Reaction Pathways in the Redox Chemistry of the [Mo(CO)2(dpe)2F]+ and [{Mo(CO)2(dpe)2}2F]3+ (dpe = Ph2P(CH2)2PPh2) Mo(II) Carbonyl Fluoride System