A
Akira Arase
Researcher at Kitami Institute of Technology
Publications - 89
Citations - 490
Akira Arase is an academic researcher from Kitami Institute of Technology. The author has contributed to research in topics: Hydroboration & Alkyl. The author has an hindex of 13, co-authored 89 publications receiving 471 citations.
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Dialkylborane-Catalyzed Hydroboration of Alkynes with 1,3,2-Benzodioxaborole in Tetrahydrofuran
TL;DR: Dialkylborane catalyzed hydroboration of alkynes with an equimolar amount of 1,3,2-benzodioxaborole in tetrahydrofuran efficiently to provide 2-alkenyl-1.3, 2.2-bioxaborol under mild reaction conditions as mentioned in this paper.
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Reactions of Organoboranes with Ferric Chloride and Thiocyanate. Convenient Syntheses of Alkyl Chlorides and Thiocyanates from Olefins via Hydroboration
TL;DR: In this article, the reactions of trialkylboranes with ferric chloride and thiocyanate in an aqueous tetrahydrofuran solution give the corresponding alkyl chlorides and thIocyanates in good yields.
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Preparation of (E)-1-Alkenylboronic Acid Pinacol Esters via Transfer of Alkenyl Group from Boron to Boron
TL;DR: In this paper, two synthetic routes to (E)-1-alkenylboronic acid pinacol esters were investigated, in situ generated by the reaction of BH 3 in THF with catechol.
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The hydroboration of 1-alkylthio-1-alkynes, and its application to the syntheses of S-alkyl alkanethioates and (Z)-1-alkylthio-1-alkenes.
TL;DR: In this article, the dialkylboryl group was added to the α-position of the triple bond of 1-alkylthio-1-alkynes with dicyclohexylborane or bis(1,2-dimethylpropyl)borane.
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The Formation of Alkyl Acetate in the Reaction of Trialkylborane with Lead(IV) Acetate or Phenyliodoso Acetate
Yuzuru Masuda,Akira Arase +1 more
TL;DR: In the reaction of trialkylborane with lead(IV) acetate or phenyliodoso acetate in benzene, about two thirds of the alkyl groups were converted to the corresponding ALkyl acetate without any isomerization.