There have been a number of review papers on layered silicate and carbon nanotube reinforced polymer nanocomposites, in which the fillers have high aspect ratios. Particulate–polymer nanocomposites containing fillers with small aspect ratios are also an important class of polymer composites. However, they have been apparently overlooked. Thus, in this paper, detailed discussions on the effects of particle size, particle/matrix interface adhesion and particle loading on the stiffness, strength and toughness of such particulate–polymer composites are reviewed. To develop high performance particulate composites, it is necessary to have some basic understanding of the stiffening, strengthening and toughening mechanisms of these composites. A critical evaluation of published experimental results in comparison with theoretical models is given.

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Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites

The Theory of Matrices. By F R. Gantmacher. Two volumes, pp. 374 and 276. 1959. (Translated from the Russian by K. A. Hirsch; Chelsea Publishing Company, New York)

A review on polymer–layered silicate nanocomposites

Unperturbed dimensions of stereoregular polymers.- Reinforcement of rubber by carbon black.- Transformations of phenolic antioxidants and the role of their products in the long-term properties of polyolefins.

Properties of polymers

Large-scale failure modes of dielectric elastomer actuators

Constitutive Models in Linear Viscoelasticity. Constitutive Models in Nonlinear Viscoelasticity. Constitutive Models in Finite Viscoelasticity. Constitutive Models in Thermoviscoelasticity. References. Index.

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Mechanics of Viscoelastic Solids

Kinematics of continua constitutive models in linear viscoelasticity nonlinear constitutive models with infinitesimal strains nonlinear constitutive models with finitie strains constitutive relations for thermoviscoelastic media accretion of ageing viscoelastic media with finite strains accretion of viscoelastic media with infinitesimal strains optimization problems for growing viscoelastic media

Viscoelastic Structures: Mechanics of Growth and Aging

Experimental data are reported on moisture diffusion and the elastoplastic response of an intercalated nanocomposite with vinyl ester resin matrix and montmorillonite clay filler at room temperature. Observations in diffusion tests show that water transport in the neat resin is Fickian, whereas it becomes anomalous (non-Fickian) with the growth of the clay content. This transition is attributed to immobilization of penetrant molecules on the surfaces of hydrophilic clay layers. Observations in uniaxial tensile tests demonstrate that the response of vinyl ester resin is strongly elastoplastic, whereas an increase in the clay content results in a severe decrease of plastic strains observed as a noticeable reduction of curvatures of the stress--strain diagrams. This is explained by slowing down of molecular mobility in the host matrix driven by confinement of chains in galleries between platelets. Constitutive equations are developed for the anomalous moisture diffusion through and the elastoplastic behavior of a nanocomposite. Adjustable parameters in these relations are found by fitting the experimental data. Fair agreement is demonstrated between the observations and the results of numerical simulation. A striking similarity is revealed between changes in diffusivity, ultimate water uptake and the rate of plastic flow with an increase in the clay content.

A model for anomalous moisture diffusion through a polymer-clay nanocomposite

This book provides a systematic and self-consistent introduction to the nonlinear continuum mechanics of solids, from the main axioms to comprehensive aspects of the theory. The objective is to expose the most intriguing aspects of elasticity and viscoelasticity with finite strains in such a way as to ensure mathematical correctness, on the one hand, and to demonstrate a wide spectrum of physical phenomena typical only of nonlinear mechanics, on the other.A novel aspect of the book is that it contains a number of examples illustrating surprising behaviour in materials with finite strains, as well as comparisons between theoretical predictions and experimental data for rubber-like polymers and elastomers.The book aims to fill a gap between mathematicians specializing in nonlinear continuum mechanics, and physicists and engineers who apply the methods of solid mechanics to a wide range of problems in civil and mechanical engineering, materials science, and polymer physics. The book has been developed from a graduate course in applied mathematics which the author has given for a number of years.

Finite Elasticity and Viscoelasticity: A Course in the Nonlinear Mechanics of Solids

Experimental data are reported on moisture diffusion and the elastoplastic response of an intercalated nanocomposite with vinyl ester resin matrix and montmorillonite clay filler at room temperature. Observations in diffusion tests showed that water transport in the neat resin is Fickian, whereas it becomes anomalous (non-Fickian) with the growth of the clay content. This transition is attributed to immobilization of penetrant molecules on the surfaces of hydrophilic clay layers. Observations in uniaxial tensile tests demonstrate that the response of vinyl ester resin is strongly elastoplastic, whereas an increase in the clay content results in a severe decrease of plastic strains observed as a noticeable reduction in the curvatures of the stress-strain diagrams. This is explained by slowing down the molecular mobility in the host matrix driven by confinement of chains in galleries between platelets. Constitutive equations are developed for moisture diffusion through and the elastoplastic behavior of a nanocomposite. Adjustable parameters in these relations are found by fitting the experimental data. Fair agreement is demonstrated between the observations and the results of numerical simulation. A striking similarity is revealed among changes in diffusivity, ultimate water uptake, and the rate of plastic flow with an increased clay content.

Aleksey D. Drozdov

Papers

Mechanics of Viscoelastic Solids

Viscoelastic Structures: Mechanics of Growth and Aging

A model for anomalous moisture diffusion through a polymer-clay nanocomposite

Finite Elasticity and Viscoelasticity: A Course in the Nonlinear Mechanics of Solids

Model for Anomalous Moisture Diffusion through a Polymer-Clay Nanocomposite