A review on polymer–layered silicate nanocomposites

A model for the axisymmetric growth and coalescence of small internal voids in elastoplastic solids is proposed and assessed using void cell computations. Two contributions existing in the literature have been integrated into the enhanced model. The first is the model of Gologanu-Leblond-Devaux, extending the Gurson model to void shape effects. The second is the approach of Thomason for the onset of void coalescence. Each of these has been extended heuristically to account for strain hardening. In addition, a micromechanically-based simple constitutive model for the void coalescence stage is proposed to supplement the criterion for the onset of coalescence. The fully enhanced Gurson model depends on the flow properties of the material and the dimensional ratios of the void-cell representative volume element. Phenomenological parameters such as critical porosities are not employed in the enhanced model. It incorporates the effect of void shape, relative void spacing, strain hardening, and porosity. The effect of the relative void spacing on void coalescence, which has not yet been carefully addressed in the literature. has received special attention. Using cell model computations, accurate predictions through final fracture have been obtained for a wide range of porosity, void spacing, initial void shape, strain hardening, and stress triaxiality. These predictions have been used to assess the enhanced model. (C) 2000 Elsevier Science Ltd. All rights reserved.

An extended model for void growth and coalescence - application to anisotropic ductile fracture

Biodegradable polymers are seen as a potential solution to the environmental problems generated by plastic waste In particular, the renewable aliphatic polyesters of poly(hydroxyacid)-type homopolymers and copolymers consisting of polylactic acid (PLA), poly(glycolic acid) (PGA), and poly(e-caprolactone) (PCL) constitute the most promising bioresorbable materials for applications in biomedical and consumer applications Among those polymers, PLA has attracted particular attention as a substitute for conventional petroleum-based plastics PLA is synthesized by the fermentation of renewable agricultural sources, including corn, cellulose, and other polysaccharides Although some of its characteristics are disadvantageous (eg, poor melt properties, mechanical brittleness, low heat resistance, and slow crystallization), there exist potential routes to resolve these shortcomings These include copolymerization, blending, plasticization modification, or the addition of reinforcing phases (eg, chitosan (Cs), cellulose, and starch) In this review, we discuss the degradation mechanisms of PLA and its modified form in the environment, current issues that hinder the achievement of good Cs/PLA combination, and ways to overcome some of these problems Furthermore, our discussion is extended to cover the subjects of hydrolytic degradation and weathering effects with different Cs/PLA blends

Hydrolytic degradation of polylactic acid (PLA) and its composites

Emerging trends in manufacturing such as light weighting, increased performance and functionality increases the use of multi-material, hybrid structures and thus the need for joining of dissimilar materials. The properties of the different materials are jointly utilised to achieve product performance. The joining processes can, on the other hand be challenging due to the same different properties. This paper reviews and summarizes state of the art research in joining dissimilar materials. Current and emerging joining technologies are reviewed according to the mechanisms of joint formation, i.e.; mechanical, chemical, thermal, or hybrid processes. Methods for process selection are described and future challenges for research on joining dissimilar materials are summarized.

/pdf/joining-of-dissimilar-materials-5d5ghi3lwg.pdf

Joining of dissimilar materials

The current global plastics economy is highly linear, with the exceptional performance and low carbon footprint of polymeric materials at odds with dramatic increases in plastic waste. Transitioning to a circular economy that retains plastic in its highest value condition is essential to reduce environmental impacts, promoting reduction, reuse, and recycling. Mechanical recycling is an essential tool in an environmentally and economically sustainable economy of plastics, but current mechanical recycling processes are limited by cost, degradation of mechanical properties, and inconsistent quality products. This review covers the current methods and challenges for the mechanical recycling of the five main packaging plastics: poly(ethylene terephthalate), polyethylene, polypropylene, polystyrene, and poly(vinyl chloride) through the lens of a circular economy. Their reprocessing induced degradation mechanisms are introduced and strategies to improve their recycling are discussed. Additionally, this review briefly examines approaches to improve polymer blending in mixed plastic waste streams and applications of lower quality recyclate.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/marc.202000415

Mechanical Recycling of Packaging Plastics: A Review.

https://backend.orbit.dtu.dk/ws/files/186061805/Eriksen_et_al._2019_ORBIT.pdf

Closing the loop for PET, PE and PP waste from households: Influence of material properties and product design for plastic recycling.

We present a new stream cipher, Rabbit, based on iterating a set of coupled non-linear functions. Rabbit is characterized by a high performance in software with a measured encryption/decryption speed of 3.7 clock cycles per byte on a Pentium III processor. We have performed detailed security analysis, in particular, correlation analysis and algebraic investigations. The cryptanalysis of Rabbit did not reveal an attack better than exhaustive key search.

/pdf/rabbit-a-new-high-performance-stream-cipher-ezdtlfk8uw.pdf

Rabbit: A New High-Performance Stream Cipher

Rabbit: A new high-performance stream cipher

Experimental data are reported on moisture diffusion and the elastoplastic response of an intercalated nanocomposite with vinyl ester resin matrix and montmorillonite clay filler at room temperature. Observations in diffusion tests show that water transport in the neat resin is Fickian, whereas it becomes anomalous (non-Fickian) with the growth of the clay content. This transition is attributed to immobilization of penetrant molecules on the surfaces of hydrophilic clay layers. Observations in uniaxial tensile tests demonstrate that the response of vinyl ester resin is strongly elastoplastic, whereas an increase in the clay content results in a severe decrease of plastic strains observed as a noticeable reduction of curvatures of the stress--strain diagrams. This is explained by slowing down of molecular mobility in the host matrix driven by confinement of chains in galleries between platelets. Constitutive equations are developed for the anomalous moisture diffusion through and the elastoplastic behavior of a nanocomposite. Adjustable parameters in these relations are found by fitting the experimental data. Fair agreement is demonstrated between the observations and the results of numerical simulation. A striking similarity is revealed between changes in diffusivity, ultimate water uptake and the rate of plastic flow with an increase in the clay content.

A model for anomalous moisture diffusion through a polymer-clay nanocomposite

Experimental data are reported on moisture diffusion and the elastoplastic response of an intercalated nanocomposite with vinyl ester resin matrix and montmorillonite clay filler at room temperature. Observations in diffusion tests showed that water transport in the neat resin is Fickian, whereas it becomes anomalous (non-Fickian) with the growth of the clay content. This transition is attributed to immobilization of penetrant molecules on the surfaces of hydrophilic clay layers. Observations in uniaxial tensile tests demonstrate that the response of vinyl ester resin is strongly elastoplastic, whereas an increase in the clay content results in a severe decrease of plastic strains observed as a noticeable reduction in the curvatures of the stress-strain diagrams. This is explained by slowing down the molecular mobility in the host matrix driven by confinement of chains in galleries between platelets. Constitutive equations are developed for moisture diffusion through and the elastoplastic behavior of a nanocomposite. Adjustable parameters in these relations are found by fitting the experimental data. Fair agreement is demonstrated between the observations and the results of numerical simulation. A striking similarity is revealed among changes in diffusivity, ultimate water uptake, and the rate of plastic flow with an increased clay content.

Jesper de Claville Christiansen

Papers

Closing the loop for PET, PE and PP waste from households: Influence of material properties and product design for plastic recycling.

Rabbit: A New High-Performance Stream Cipher

Rabbit: A new high-performance stream cipher

A model for anomalous moisture diffusion through a polymer-clay nanocomposite

Model for Anomalous Moisture Diffusion through a Polymer-Clay Nanocomposite