Electroactive phases of poly(vinylidene fluoride) : determination, processing and applications

Dielectric polymer nanocomposites are rapidly emerging as novel materials for a number of advanced engineering applications. In this Review, we present a comprehensive review of the use of ferroelectric polymers, especially PVDF and PVDF-based copolymers/blends as potential components in dielectric nanocomposite materials for high energy density capacitor applications. Various parameters like dielectric constant, dielectric loss, breakdown strength, energy density, and flexibility of the polymer nanocomposites have been thoroughly investigated. Fillers with different shapes have been found to cause significant variation in the physical and electrical properties. Generally, one-dimensional and two-dimensional nanofillers with large aspect ratios provide enhanced flexibility versus zero-dimensional fillers. Surface modification of nanomaterials as well as polymers adds flavor to the dielectric properties of the resulting nanocomposites. Nowadays, three-phase nanocomposites with either combination of fillers...

Recent Progress on Ferroelectric Polymer-Based Nanocomposites for High Energy Density Capacitors: Synthesis, Dielectric Properties, and Future Aspects.

In 1982, the Belgian Pilots' Guild raised the question of what effect exposure to radar radiation--for example, that encountered in passing a pilot launch's radar--might have on the human body. Recapitulating investigations of this question, this article states that in 25 years of experience with radar, there have been no known incidents of pilots being affected by radar waves. In the future, however, involvement by some pilots with Vessel Traffic Service shore-based radar could affect pilots somewhat differently from limited exposure to pilot launch radar. Pilots who find themselves in new working conditions close to an emitting source should exercise care all times.

About heat waves

Reversible crystallization and the rigid-amorphous phase in semicrystalline macromolecules

Polymers are widely used in industry and in our daily life because of their diverse functionality, light weight, low cost and excellent chemical stability. However, on some applications such as heat exchangers and electronic packaging, the low thermal conductivity of polymers is one of the major technological barriers. Enhancing the thermal conductivity of polymers is important for these applications and has become a very active research topic over the past two decades. In this review article, we aim to: 1). systematically summarize the molecular level understanding on the thermal transport mechanisms in polymers in terms of polymer morphology, chain structure and inter-chain coupling; 2). highlight the rationales in the recent efforts in enhancing the thermal conductivity of nanostructured polymers and polymer nanocomposites. Finally, we outline the main advances, challenges and outlooks for highly thermal-conductive polymer and polymer nanocomposites.

Thermal conductivity of polymers and polymer nanocomposites

Melting and reorganization of poly(ethylene terephthalate) on fast heating (1000 K/s)

Scanning microcalorimetry at high cooling rate

To generate artificial materials with advanced physical and chemical properties and to study phase transition kinetics on submillisecond time scale, an ultrafast nonadiabatic membrane nanocalorimeter was constructed. A set of commercially available membrane gauges for ultrafast nanocalorimetry has been developed. The gauges placed in a thermostat with controlled helium gas pressure and temperature can be utilized as devices for thermal processing and calorimetry with resolution of 1nJ∕K. Controlled ultrafast cooling, as well as heating, up to 106K∕s can be attained for nanogram samples. The maximum cooling rate is inversely proportional to the radius of the heated region of the gauge, which was in the range of 10–100μm depending on the gauge. The minimum addenda heat capacity was 3nJ∕K. The dynamic heat-transfer problem for the temperature distribution in the membrane-gas system at ultrafast processing has been solved. The characteristic rate R0 corresponding to quasistatic limit of the temperature change...

Ultrafast thermal processing and nanocalorimetry at heating and cooling rates up to 1 MK/s

A differential AC-chip calorimeter capable of measuring the step in heat capacity at the glass transition in nanometer-thin films is described. Because of the differential setup, pJ/K sensitivity is achieved. Heat capacity can be measured for sample masses below 1 ng in broad temperature range as needed for the study of the glass transition in nanometer-thin polymeric films. Relative accuracy is sufficient to investigate the changes in heat capacity as the step at the glass transition of polystyrene. The step is about 25% of the total heat capacity of polystyrene. The calorimeter allows for the frequency dependent measurement of complex heat capacity in the frequency range from 1 Hz to 1 kHz. The glass transition in thin polystyrene films (50–4 nm) was determined at well-defined experimental time scales. No thickness dependency of the glass transition temperature was observed within the error limits (±3 K)—neither at constant frequency (40 Hz) nor for the trace in the activation diagram (1 Hz–1 kHz). © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2996–3005, 2006

Alexander A. Minakov

Papers

Melting and reorganization of poly(ethylene terephthalate) on fast heating (1000 K/s)

Scanning microcalorimetry at high cooling rate

Ultrafast thermal processing and nanocalorimetry at heating and cooling rates up to 1 MK/s

Differential AC-chip calorimeter for glass transition measurements in ultrathin films

Non-adiabatic thin-film (chip) nanocalorimetry