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Alexsandr I. Yanovsky
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 4
Citations - 51
Alexsandr I. Yanovsky is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Alkoxide & Trigonal bipyramidal molecular geometry. The author has an hindex of 3, co-authored 4 publications receiving 49 citations.
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Journal ArticleDOI
Physicochemical approach to the studies of metal alkoxides
N. Ya. Turova,E. P. Turevskaya,M. I. Yanovskaya,Alexsandr I. Yanovsky,Vadim G. Kessler,D.E. Tcheboukov +5 more
TL;DR: In this article, a review of the main events in the development of metal alkoxides in Russian and summarizes the results obtained by the authors has been provided, including the analysis of solubility and vapor pressure in the M(OR)n-ROH (R Li, Mg, Ca, Sr, Ba, Tl) systems permitted the determination of the composition of the solvates formed and the optimization of the isolation conditions for distinct derivatives.
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The structure of the LiOMe·2MeOH crystal solvate. A new structural type for tetrameric alkoxides
TL;DR: The solvate LiOMe·2MeOH (1) was isolated from a solution of LiOme in MeOH, its tetrameric unit [Li4(μ-OR)4 (μ-ROH)2(ROH4]·2ROH may be described as two distorted squares [Li2(μ -OR)(μ -ROH), linked by bridging alkoxy groups and two hydrogen bonds as mentioned in this paper.
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Isolation and structural characterization of the first homoleptic lanthanide–zirconium oxoisopropoxide, La2Zr3O(OPri)16. Combination of an [M4O] tetrahedron with an [MO6] octahedron – A new structure type for pentanuclear alkoxide complexes
TL;DR: In this article, the amorphous bimetallic isopropoxides of variable composition LaZr n O x (OPr i ) 3+4 n −2 x, where n ǫ = 0.5 −3 formed on interaction of the two homometallic isopsides, La 5 O(O i Pr) 13 and Zr(O I Pr) 4 ( i PrOH), in solutions in parent alcohol crystallize slowly yielding a bimetal oxoalkoxide La 2 Zr 3 O(OPr I ) 16 ( 1 ).
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On the structure of heterometallic methoxide Li2(WO)2(OMe)10·MeOH
TL;DR: The structure of I as determined by the X-ray diffraction (XRD) method features infinite chains made up of two alternating tetranuclear species [Li2WO]2(OMe)10] (A) and [Li 2WO)2OMe10(MeOH)2] (B), linked via LiOW bridges involving the Li atom belonging to fragment A and tungstenyl group from fragment B as discussed by the authors.