Journal ArticleDOI
On the structure of heterometallic methoxide Li2(WO)2(OMe)10·MeOH
TLDR
The structure of I as determined by the X-ray diffraction (XRD) method features infinite chains made up of two alternating tetranuclear species [Li2WO]2(OMe)10] (A) and [Li 2WO)2OMe10(MeOH)2] (B), linked via LiOW bridges involving the Li atom belonging to fragment A and tungstenyl group from fragment B as discussed by the authors.About:
This article is published in Polyhedron.The article was published on 2002-01-30. It has received 1 citations till now. The article focuses on the topics: Methoxide & Trigonal bipyramidal molecular geometry.read more
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Co-crystals, Salts, and Ionic Co-crystals of Ethanol and Ammonia
TL;DR: In this article, solid crystalline specimens of molecular ethanol mono-ammoniate and etha-mono-acetylene compounds have been found, but no structural characterization has been carried out.
References
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Journal ArticleDOI
The crystal and molecular structure of titanium tetramethoxide
D. A. Wright,D. A. Williams +1 more
Journal ArticleDOI
Molybdenum and tungsten (VI) bimetallic alkoxides. Decomposition accompanied by dialkylether elimination
TL;DR: In this paper, the existence of (1:1) bimetallic complexes in alcohol solutions has been proved by conductometric titration curves of MO(OR)4, and MO2 (OR)2 (M = Mo, W; R = Et, iPr, C2H4OMe) by sodium (or lithium) alkoxides.
Journal ArticleDOI
Solid state and solution studies of tungsten(VI) oxotetraalkoxides
TL;DR: In this paper, variable-temperature 1H NMR studies of oxoalkoxides, WO(OR)4(R = Me, Et, Pri, or cyclo-C6H11), show these compounds to be dynamic in solution.
Journal ArticleDOI
Anodic oxidation of molybdenum and tungsten in alcohols: isolation and X-ray single-crystal study of side products
Vadim G. Kessler,Andrei N. Panov,Nataliya Ya. Turova,Zoya A. Starikova,Alexandr I. Yanovsky,Fedor M. Dolgushin,A. P. Pisarevsky,Yuri T. Struchkov +7 more
TL;DR: In this paper, the side products of the anodic dissolution of molybdenum and tungsten metals in alcohols in the presence of LiCl showed them to be [LiMo2O4(OPri)4(OC2H4OMe)] 1 in the case of MeOH and [ LiMo2OC4(OEt)5(EtOH)] 2 in EtOH.
Journal ArticleDOI
The structure of the LiOMe·2MeOH crystal solvate. A new structural type for tetrameric alkoxides
TL;DR: The solvate LiOMe·2MeOH (1) was isolated from a solution of LiOme in MeOH, its tetrameric unit [Li4(μ-OR)4 (μ-ROH)2(ROH4]·2ROH may be described as two distorted squares [Li2(μ -OR)(μ -ROH), linked by bridging alkoxy groups and two hydrogen bonds as mentioned in this paper.