Journal ArticleDOI
Isolation and structural characterization of the first homoleptic lanthanide–zirconium oxoisopropoxide, La2Zr3O(OPri)16. Combination of an [M4O] tetrahedron with an [MO6] octahedron – A new structure type for pentanuclear alkoxide complexes
TLDR
In this article, the amorphous bimetallic isopropoxides of variable composition LaZr n O x (OPr i ) 3+4 n −2 x, where n ǫ = 0.5 −3 formed on interaction of the two homometallic isopsides, La 5 O(O i Pr) 13 and Zr(O I Pr) 4 ( i PrOH), in solutions in parent alcohol crystallize slowly yielding a bimetal oxoalkoxide La 2 Zr 3 O(OPr I ) 16 ( 1 ).About:
This article is published in Inorganic Chemistry Communications.The article was published on 2007-03-01. It has received 4 citations till now. The article focuses on the topics: Alkoxide & Octahedron.read more
Citations
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A Pentanuclear Cu/Co/Ni Complex with 2‐(Dimethylamino)ethanol – Observation of a Rare Molecular Structure Type and Its Place in General Structural Types: An Analysis of the Cambridge Structural Database
TL;DR: In this article, a pentanuclear molecule is formed by a previously unknown combination of incomplete cube M3(μ3-X)(μ-X)3 and triangle bipyramidal M3 (μ3X)2(μ-x)2 fragments, resulting in a zigzag arrangement of metal centers within one molecule.
Journal ArticleDOI
Titanium, zirconium and hafnium
TL;DR: A review of the literature reported during 2007 on titanium, zirconium and hafnium can be found in this article, where the authors present a very selective review, and much fine work has not been cited.
Journal ArticleDOI
Heterometallic Group 4-Lanthanide Oxo-alkoxide Precursors for Synthesis of Binary Oxide Nanomaterials.
TL;DR: This procedure gave crystalline precursors with molecular stoichiometries suitable for obtaining group 4-lanthanide oxide materials and indicated weak antiferromagnetic interactions between NdIII ions and a field-supported slow magnetic relaxation.
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Lanthanum alkoxides. Crystal structure of [La 6 (μ 6 -Cl)(μ 3 -OPr i ) 2 (μ-OPr i ) 9 (OPr i ) 6 ]
TL;DR: In this article, the synthesis of lanthanum isopropoxide has been studied in the presence of I2 or a HgCl2/HgI2/hg(OAc)2 mixture catalysts or Bu4NBr or Et3BzNCl electrochemical additives, respectively.
References
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Journal ArticleDOI
Alcohol adducts of alkoxides: intramolecular hydrogen bonding as a general structural feature
Brian A. Vaartstra,John C. Huffman,Kenneth G. Caulton,Peter S. Gradeff,Kenan Yunlu,L.G. Hubert-Pfalzgraf,S. Parraud,Jean-Claude Daran +7 more
TL;DR: In this article, a characterization of Zr{sub 2}(O{sup i}Pr), sub 8}(sup i)PrOH, sub 2} by {sup 1}H and {sup 13}C NMR spectroscopy, ir spectroscopic, and single-crystal x-ray diffraction is reported.
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Volatile Metal Alkoxides according to the Concept of Donor Functionalization
TL;DR: A detailed inventory of the metal alkoxides with particular regard to the aspect of volatility can be found in this article, where the concept of donor functionalization has been applied to a wide range of metal ligands.
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New perspectives in the tailoring of hetero (bi- and tri-) metallic alkoxide derivatives
TL;DR: In this article, the structural properties and applications of hetero(bi-and tri-)metallic alkoxides with halides and cyclopentadienyl ligands are discussed.
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Volatile tris-tertiary-alkoxides of yttrium and lanthanum. The x-ray crystal structure of [La3(OBut)9(ButOH)2]
TL;DR: In this article, the tertiary alkoxides of yttrium and lanthanum have been prepared by adding excess tertiary alcohol to the metal tris-(bistrimethylsilylamides), M{N(SiMe3)2}3 (M = Y, La), and characterized by elemental analyses, NMR, IR and mass spectroscopy.